The crystal structures of 3-O-benzyl-1,2-O-isopropylidene-5-O-methanesulfonyl-6-O-triphenylmethyl-α-d-glucofuranose and its azide displacement product

The crystal structures of 3-O-benzyl-1,2-O-isopropylidene-5-O-methanesulfonyl-6-O-triphenylmethyl-α-d-glucofuranose and its azide displacement product

The effect of different leaving groups on the substitution versus elimination outcomes with C-5 d-glucose derivatives was investigated. The stereochemical configurations of 3-O-benzyl-1,2-O-isopropylidene-5-O-methanesulfonyl-6-O-triphenylmethyl-α-d-glucofuranose, C36H38O8S (3) [systematic name: 1-[(...

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Bibliographic Details
Main Authors: Zane Clarke, Evan Barnes, Kate L. Prichard, Laura J. Mares, Jack K. Clegg, Adam McCluskey, Todd A. Houston, Michela I. Simone
Format: Article
Language:English
Published: International Union of Crystallography 2018-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
iminosugar
D-glucofuranose
elimination
substitution
hydrogen bonding
C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901800765X

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