Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate

Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate

In the title complex, [Pt(C15H11N4O)Cl3]·CH3CN, the PtIV ion adopts a distorted octahedral coordination geometry defined by a tridentate cyclometalated NCN ligand and three Cl atoms. In the crystal, individual molecules are aggregated into a three-dimensional network by C—...

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Main Authors: Yang Wu, Dahai Xie, Dengqing Zhang, Xianying Li, Wusong Jin
Format: Article
Language:English
Published: International Union of Crystallography 2012-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812036410
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spelling doaj-1ace648eb9ec4b599eb6de05361c0dff2020-11-24T21:28:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1210m121110.1107/S1600536812036410Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvateYang WuDahai XieDengqing ZhangXianying LiWusong JinIn the title complex, [Pt(C15H11N4O)Cl3]·CH3CN, the PtIV ion adopts a distorted octahedral coordination geometry defined by a tridentate cyclometalated NCN ligand and three Cl atoms. In the crystal, individual molecules are aggregated into a three-dimensional network by C—H...Cl hydrogen-bonding interactions and π–π stacking interactions between the tridentate ligands, the shortest ring centroid–centroid distance being 3.613 Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812036410
collection DOAJ
language English
format Article
sources DOAJ
author Yang Wu
Dahai Xie
Dengqing Zhang
Xianying Li
Wusong Jin
spellingShingle Yang Wu
Dahai Xie
Dengqing Zhang
Xianying Li
Wusong Jin
Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate
Acta Crystallographica Section E
author_facet Yang Wu
Dahai Xie
Dengqing Zhang
Xianying Li
Wusong Jin
author_sort Yang Wu
title Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate
title_short Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate
title_full Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate
title_fullStr Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate
title_full_unstemmed Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate
title_sort trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κn)phenyl-κc1]platinum(iv) acetonitrile monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-09-01
description In the title complex, [Pt(C15H11N4O)Cl3]·CH3CN, the PtIV ion adopts a distorted octahedral coordination geometry defined by a tridentate cyclometalated NCN ligand and three Cl atoms. In the crystal, individual molecules are aggregated into a three-dimensional network by C—H...Cl hydrogen-bonding interactions and π–π stacking interactions between the tridentate ligands, the shortest ring centroid–centroid distance being 3.613 Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812036410
work_keys_str_mv AT yangwu trichlorido4methoxy26bis2pyrimidin2ylamp954nphenylamp954c1platinumivacetonitrilemonosolvate
AT dahaixie trichlorido4methoxy26bis2pyrimidin2ylamp954nphenylamp954c1platinumivacetonitrilemonosolvate
AT dengqingzhang trichlorido4methoxy26bis2pyrimidin2ylamp954nphenylamp954c1platinumivacetonitrilemonosolvate
AT xianyingli trichlorido4methoxy26bis2pyrimidin2ylamp954nphenylamp954c1platinumivacetonitrilemonosolvate
AT wusongjin trichlorido4methoxy26bis2pyrimidin2ylamp954nphenylamp954c1platinumivacetonitrilemonosolvate
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