Influence of Varied Fluorine Contents on Long-Term Storage Stability of Polyacrylate Nanoparticles and Film Properties

Polyacrylate nanoparticles are widely applied and typically prepared by many polymerization methods. However, poor long-term storage stability of nanoparticles limited their use, so some methods are carried out to overcome it. In this paper, we investigated a series of fluorinated polyacrylate nanop...

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Main Authors: Hongzhu Liu, Gaofan Zhang, Lulu Lu, Yuexing Chen, Mengting Luo, Jiming Bian, Zefeng Wang, Lijin Wang
Format: Article
Language:English
Published: Hindawi Limited 2019-01-01
Series:Journal of Nanomaterials
Online Access:http://dx.doi.org/10.1155/2019/2970819
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spelling doaj-1aca5878e2e74eb4ae1f84307df77f0c2020-11-25T01:20:37ZengHindawi LimitedJournal of Nanomaterials1687-41101687-41292019-01-01201910.1155/2019/29708192970819Influence of Varied Fluorine Contents on Long-Term Storage Stability of Polyacrylate Nanoparticles and Film PropertiesHongzhu Liu0Gaofan Zhang1Lulu Lu2Yuexing Chen3Mengting Luo4Jiming Bian5Zefeng Wang6Lijin Wang7School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, ChinaWenzhou Institute, University of Chinese Academy of Sciences (Wenzhou Institute of Biomaterials & Engineering), Wenzhou 325001, ChinaSchool of Biological Science and Engineering, South China University of Technology, Guangzhou 510640, ChinaDepartment of Chemistry, Lishui University, Lishui 323000, ChinaDepartment of Chemistry, Lishui University, Lishui 323000, ChinaKey Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics, Dalian University of Technology, Dalian 116024, ChinaDepartment of Chemistry, Lishui University, Lishui 323000, ChinaDepartment of Chemistry, Lishui University, Lishui 323000, ChinaPolyacrylate nanoparticles are widely applied and typically prepared by many polymerization methods. However, poor long-term storage stability of nanoparticles limited their use, so some methods are carried out to overcome it. In this paper, we investigated a series of fluorinated polyacrylate nanoparticles to improve the long-term storage stability of polyacrylate nanoparticles. We found that increasing fluorine content resists the aggregation of nanoparticles during long-term storage. Furthermore, a higher content of fluorine can improve the hydrophobicity of latex polyacrylate film and increase the refractive index of latex polyacrylate film. The properties of the polyacrylate nanoparticles and latex film can thus be controlled by changing fluorine contents, which in turn provides key insights into the design of functional polymer material.http://dx.doi.org/10.1155/2019/2970819
collection DOAJ
language English
format Article
sources DOAJ
author Hongzhu Liu
Gaofan Zhang
Lulu Lu
Yuexing Chen
Mengting Luo
Jiming Bian
Zefeng Wang
Lijin Wang
spellingShingle Hongzhu Liu
Gaofan Zhang
Lulu Lu
Yuexing Chen
Mengting Luo
Jiming Bian
Zefeng Wang
Lijin Wang
Influence of Varied Fluorine Contents on Long-Term Storage Stability of Polyacrylate Nanoparticles and Film Properties
Journal of Nanomaterials
author_facet Hongzhu Liu
Gaofan Zhang
Lulu Lu
Yuexing Chen
Mengting Luo
Jiming Bian
Zefeng Wang
Lijin Wang
author_sort Hongzhu Liu
title Influence of Varied Fluorine Contents on Long-Term Storage Stability of Polyacrylate Nanoparticles and Film Properties
title_short Influence of Varied Fluorine Contents on Long-Term Storage Stability of Polyacrylate Nanoparticles and Film Properties
title_full Influence of Varied Fluorine Contents on Long-Term Storage Stability of Polyacrylate Nanoparticles and Film Properties
title_fullStr Influence of Varied Fluorine Contents on Long-Term Storage Stability of Polyacrylate Nanoparticles and Film Properties
title_full_unstemmed Influence of Varied Fluorine Contents on Long-Term Storage Stability of Polyacrylate Nanoparticles and Film Properties
title_sort influence of varied fluorine contents on long-term storage stability of polyacrylate nanoparticles and film properties
publisher Hindawi Limited
series Journal of Nanomaterials
issn 1687-4110
1687-4129
publishDate 2019-01-01
description Polyacrylate nanoparticles are widely applied and typically prepared by many polymerization methods. However, poor long-term storage stability of nanoparticles limited their use, so some methods are carried out to overcome it. In this paper, we investigated a series of fluorinated polyacrylate nanoparticles to improve the long-term storage stability of polyacrylate nanoparticles. We found that increasing fluorine content resists the aggregation of nanoparticles during long-term storage. Furthermore, a higher content of fluorine can improve the hydrophobicity of latex polyacrylate film and increase the refractive index of latex polyacrylate film. The properties of the polyacrylate nanoparticles and latex film can thus be controlled by changing fluorine contents, which in turn provides key insights into the design of functional polymer material.
url http://dx.doi.org/10.1155/2019/2970819
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AT gaofanzhang influenceofvariedfluorinecontentsonlongtermstoragestabilityofpolyacrylatenanoparticlesandfilmproperties
AT lululu influenceofvariedfluorinecontentsonlongtermstoragestabilityofpolyacrylatenanoparticlesandfilmproperties
AT yuexingchen influenceofvariedfluorinecontentsonlongtermstoragestabilityofpolyacrylatenanoparticlesandfilmproperties
AT mengtingluo influenceofvariedfluorinecontentsonlongtermstoragestabilityofpolyacrylatenanoparticlesandfilmproperties
AT jimingbian influenceofvariedfluorinecontentsonlongtermstoragestabilityofpolyacrylatenanoparticlesandfilmproperties
AT zefengwang influenceofvariedfluorinecontentsonlongtermstoragestabilityofpolyacrylatenanoparticlesandfilmproperties
AT lijinwang influenceofvariedfluorinecontentsonlongtermstoragestabilityofpolyacrylatenanoparticlesandfilmproperties
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