Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}

Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}

The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a pentamethylcyclop...

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Bibliographic Details
Main Authors: Adrián Pérez-Redondo, Avelino Martín
Format: Article
Language:English
Published: International Union of Crystallography 2015-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
titanium oxide
pentamethylcyclopentadienyl ligand
organometallic
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015004041
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spelling doaj-19f98048e9aa4607adde5d2c19ddd45d2020-11-24T23:28:11ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-04-01714m97m9710.1107/S2056989015004041rz5150Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}Adrián Pérez-Redondo0Avelino Martín1Química Inorgánica, Universidad de Alcalá, Campus Universitario, ES 28871 Alcalá de Henares (Madrid), SpainQuímica Inorgánica, Universidad de Alcalá, Campus Universitario, ES 28871 Alcalá de Henares (Madrid), SpainThe title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a pentamethylcyclopentadienyl ligand linked in an η5-coordination fashion, while three bridging O atoms fill the other three sites.http://scripts.iucr.org/cgi-bin/paper?S2056989015004041crystal structuretitanium oxidepentamethylcyclopentadienyl ligandorganometallic
collection DOAJ
language English
format Article
sources DOAJ
author Adrián Pérez-Redondo
Avelino Martín
spellingShingle Adrián Pérez-Redondo
Avelino Martín
Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
titanium oxide
pentamethylcyclopentadienyl ligand
organometallic
author_facet Adrián Pérez-Redondo
Avelino Martín
author_sort Adrián Pérez-Redondo
title Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
title_short Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
title_full Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
title_fullStr Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
title_full_unstemmed Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
title_sort crystal structure of μ-oxido-1,1′κ2o:o-bis{tetra-μ-oxido-1:2κ2o:o;1:3κ2o:o;2:3κ4o:o-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(iv)}
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-04-01
description The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a pentamethylcyclopentadienyl ligand linked in an η5-coordination fashion, while three bridging O atoms fill the other three sites.
topic crystal structure
titanium oxide
pentamethylcyclopentadienyl ligand
organometallic
url http://scripts.iucr.org/cgi-bin/paper?S2056989015004041
work_keys_str_mv AT adrianperezredondo crystalstructureofmoxido11k2oobistetramoxido12k2oo13k2oo23k4ootris123ē5pentamethylcyclopentadienyltrianglotrititaniumiv
AT avelinomartin crystalstructureofmoxido11k2oobistetramoxido12k2oo13k2oo23k4ootris123ē5pentamethylcyclopentadienyltrianglotrititaniumiv
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