Crystal structures and Hirshfeld surface analysis of trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ2N,N′}manganese(II) and trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ2N,N′}nickel(II))

Crystal structures and Hirshfeld surface analysis of trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ2N,N′}manganese(II) and trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ2N,N′}nickel(II))

Two new mononuclear metal complexes involving the bidentate Schiff base ligand 2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline (C15H16N2 or PM-TMA), [Mn(NCS)2(PM-TMA)2] (I) and [Ni(NCS)2(PM-TMA)2] (II), were synthesized and their structures determined by single-crystal X-ray diffraction. Althou...

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Bibliographic Details
Main Authors: Siripak Jittirattanakun, Chatphorn Theppitak, Nanthawat Wannarit, Bachari Rotsut, Kittipong Chainok
Format: Article
Language:English
Published: International Union of Crystallography 2020-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
manganese(ii)
nickel(ii)
schiff base
weak intermolecular interactions
hirshfeld surface analysis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020000870

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http://scripts.iucr.org/cgi-bin/paper?S2056989020000870

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