Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives
Semi-rigid composites of polyurethane foams (SRPUF) modified with the addition of keratin flour from poultry feathers and flame retardant additives were manufactured. Ten percent by mass of keratin fibers was added to the foams as well as halogen-free flame retardant additives such as Fyrol PNX, exp...
Main Authors: | , , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-12-01
|
Series: | Polymers |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4360/12/12/2943 |
id |
doaj-1934deb7f4ba46a5827f5b5b374961f2 |
---|---|
record_format |
Article |
spelling |
doaj-1934deb7f4ba46a5827f5b5b374961f22020-12-10T00:05:20ZengMDPI AGPolymers2073-43602020-12-01122943294310.3390/polym12122943Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant AdditivesKrystyna Wrześniewska-Tosik0Joanna Ryszkowska1Tomasz Mik2Ewa Wesołowska3Tomasz Kowalewski4Michalina Pałczyńska5Kamila Sałasińska6Damian Walisiak7Anna Czajka8Łukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandFaculty of Materials Science, Warsaw University of Technology, Woloska 141, 02-507 Warszawa, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandDepartment of Chemical, Biological and Aerosol Hazards, Central Institute for Labor Protection, National Research Institute, Czerniakowska 16 00-701 Warsaw, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandFaculty of Materials Science, Warsaw University of Technology, Woloska 141, 02-507 Warszawa, PolandSemi-rigid composites of polyurethane foams (SRPUF) modified with the addition of keratin flour from poultry feathers and flame retardant additives were manufactured. Ten percent by mass of keratin fibers was added to the foams as well as halogen-free flame retardant additives such as Fyrol PNX, expandable graphite, metal oxides, in amounts such that their total mass did not exceed 15%. Thermal and mechanical properties were tested. Water absorption, dimensional stability, apparent density and flammability of produced foams were determined. It was found that the use of keratin fibers and flame retardant additives changes the foam synthesis process, changes their structure and properties as well as their combustion process. The addition of the filler made of keratin fibers significantly limits the amount of smoke generated during foam burning. The most favorable reduction of heat and smoke release rate was observed for foams with the addition of 10% keratin fibers and 10% expandable graphite. Systems of reducing combustibility of polyurethane foams using keratin fillers are a new solution on a global scale.https://www.mdpi.com/2073-4360/12/12/2943semi-rigid polyurethane foams (SRPUF)keratin flour (CF)flame retardantscombustibility |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Krystyna Wrześniewska-Tosik Joanna Ryszkowska Tomasz Mik Ewa Wesołowska Tomasz Kowalewski Michalina Pałczyńska Kamila Sałasińska Damian Walisiak Anna Czajka |
spellingShingle |
Krystyna Wrześniewska-Tosik Joanna Ryszkowska Tomasz Mik Ewa Wesołowska Tomasz Kowalewski Michalina Pałczyńska Kamila Sałasińska Damian Walisiak Anna Czajka Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives Polymers semi-rigid polyurethane foams (SRPUF) keratin flour (CF) flame retardants combustibility |
author_facet |
Krystyna Wrześniewska-Tosik Joanna Ryszkowska Tomasz Mik Ewa Wesołowska Tomasz Kowalewski Michalina Pałczyńska Kamila Sałasińska Damian Walisiak Anna Czajka |
author_sort |
Krystyna Wrześniewska-Tosik |
title |
Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives |
title_short |
Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives |
title_full |
Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives |
title_fullStr |
Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives |
title_full_unstemmed |
Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives |
title_sort |
composites of semi-rigid polyurethane foams with keratin fibers derived from poultry feathers and flame retardant additives |
publisher |
MDPI AG |
series |
Polymers |
issn |
2073-4360 |
publishDate |
2020-12-01 |
description |
Semi-rigid composites of polyurethane foams (SRPUF) modified with the addition of keratin flour from poultry feathers and flame retardant additives were manufactured. Ten percent by mass of keratin fibers was added to the foams as well as halogen-free flame retardant additives such as Fyrol PNX, expandable graphite, metal oxides, in amounts such that their total mass did not exceed 15%. Thermal and mechanical properties were tested. Water absorption, dimensional stability, apparent density and flammability of produced foams were determined. It was found that the use of keratin fibers and flame retardant additives changes the foam synthesis process, changes their structure and properties as well as their combustion process. The addition of the filler made of keratin fibers significantly limits the amount of smoke generated during foam burning. The most favorable reduction of heat and smoke release rate was observed for foams with the addition of 10% keratin fibers and 10% expandable graphite. Systems of reducing combustibility of polyurethane foams using keratin fillers are a new solution on a global scale. |
topic |
semi-rigid polyurethane foams (SRPUF) keratin flour (CF) flame retardants combustibility |
url |
https://www.mdpi.com/2073-4360/12/12/2943 |
work_keys_str_mv |
AT krystynawrzesniewskatosik compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives AT joannaryszkowska compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives AT tomaszmik compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives AT ewawesołowska compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives AT tomaszkowalewski compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives AT michalinapałczynska compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives AT kamilasałasinska compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives AT damianwalisiak compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives AT annaczajka compositesofsemirigidpolyurethanefoamswithkeratinfibersderivedfrompoultryfeathersandflameretardantadditives |
_version_ |
1724387716197515264 |