Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives

Semi-rigid composites of polyurethane foams (SRPUF) modified with the addition of keratin flour from poultry feathers and flame retardant additives were manufactured. Ten percent by mass of keratin fibers was added to the foams as well as halogen-free flame retardant additives such as Fyrol PNX, exp...

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Main Authors: Krystyna Wrześniewska-Tosik, Joanna Ryszkowska, Tomasz Mik, Ewa Wesołowska, Tomasz Kowalewski, Michalina Pałczyńska, Kamila Sałasińska, Damian Walisiak, Anna Czajka
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/12/12/2943
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spelling doaj-1934deb7f4ba46a5827f5b5b374961f22020-12-10T00:05:20ZengMDPI AGPolymers2073-43602020-12-01122943294310.3390/polym12122943Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant AdditivesKrystyna Wrześniewska-Tosik0Joanna Ryszkowska1Tomasz Mik2Ewa Wesołowska3Tomasz Kowalewski4Michalina Pałczyńska5Kamila Sałasińska6Damian Walisiak7Anna Czajka8Łukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandFaculty of Materials Science, Warsaw University of Technology, Woloska 141, 02-507 Warszawa, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandDepartment of Chemical, Biological and Aerosol Hazards, Central Institute for Labor Protection, National Research Institute, Czerniakowska 16 00-701 Warsaw, PolandŁukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres, ul Skłodowskiej-Curie 19/27, 90-570 Łód’z, PolandFaculty of Materials Science, Warsaw University of Technology, Woloska 141, 02-507 Warszawa, PolandSemi-rigid composites of polyurethane foams (SRPUF) modified with the addition of keratin flour from poultry feathers and flame retardant additives were manufactured. Ten percent by mass of keratin fibers was added to the foams as well as halogen-free flame retardant additives such as Fyrol PNX, expandable graphite, metal oxides, in amounts such that their total mass did not exceed 15%. Thermal and mechanical properties were tested. Water absorption, dimensional stability, apparent density and flammability of produced foams were determined. It was found that the use of keratin fibers and flame retardant additives changes the foam synthesis process, changes their structure and properties as well as their combustion process. The addition of the filler made of keratin fibers significantly limits the amount of smoke generated during foam burning. The most favorable reduction of heat and smoke release rate was observed for foams with the addition of 10% keratin fibers and 10% expandable graphite. Systems of reducing combustibility of polyurethane foams using keratin fillers are a new solution on a global scale.https://www.mdpi.com/2073-4360/12/12/2943semi-rigid polyurethane foams (SRPUF)keratin flour (CF)flame retardantscombustibility
collection DOAJ
language English
format Article
sources DOAJ
author Krystyna Wrześniewska-Tosik
Joanna Ryszkowska
Tomasz Mik
Ewa Wesołowska
Tomasz Kowalewski
Michalina Pałczyńska
Kamila Sałasińska
Damian Walisiak
Anna Czajka
spellingShingle Krystyna Wrześniewska-Tosik
Joanna Ryszkowska
Tomasz Mik
Ewa Wesołowska
Tomasz Kowalewski
Michalina Pałczyńska
Kamila Sałasińska
Damian Walisiak
Anna Czajka
Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives
Polymers
semi-rigid polyurethane foams (SRPUF)
keratin flour (CF)
flame retardants
combustibility
author_facet Krystyna Wrześniewska-Tosik
Joanna Ryszkowska
Tomasz Mik
Ewa Wesołowska
Tomasz Kowalewski
Michalina Pałczyńska
Kamila Sałasińska
Damian Walisiak
Anna Czajka
author_sort Krystyna Wrześniewska-Tosik
title Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives
title_short Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives
title_full Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives
title_fullStr Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives
title_full_unstemmed Composites of Semi-Rigid Polyurethane Foams with Keratin Fibers Derived from Poultry Feathers and Flame Retardant Additives
title_sort composites of semi-rigid polyurethane foams with keratin fibers derived from poultry feathers and flame retardant additives
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2020-12-01
description Semi-rigid composites of polyurethane foams (SRPUF) modified with the addition of keratin flour from poultry feathers and flame retardant additives were manufactured. Ten percent by mass of keratin fibers was added to the foams as well as halogen-free flame retardant additives such as Fyrol PNX, expandable graphite, metal oxides, in amounts such that their total mass did not exceed 15%. Thermal and mechanical properties were tested. Water absorption, dimensional stability, apparent density and flammability of produced foams were determined. It was found that the use of keratin fibers and flame retardant additives changes the foam synthesis process, changes their structure and properties as well as their combustion process. The addition of the filler made of keratin fibers significantly limits the amount of smoke generated during foam burning. The most favorable reduction of heat and smoke release rate was observed for foams with the addition of 10% keratin fibers and 10% expandable graphite. Systems of reducing combustibility of polyurethane foams using keratin fillers are a new solution on a global scale.
topic semi-rigid polyurethane foams (SRPUF)
keratin flour (CF)
flame retardants
combustibility
url https://www.mdpi.com/2073-4360/12/12/2943
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