Bis(acetonitrile-κN)diaquabis(perchlorato-κO)copper(II)

Bis(acetonitrile-κN)diaquabis(perchlorato-κO)copper(II)

In the title compound, [Cu(ClO4)2(CH3CN)2(H2O)2], the Cu2+ ion, located on a special position (site symmetry overline{1}), is coordinated by six monodentate ligands, viz. an N-coordinated acetonitrile, a perchlorate anion and a water molecule, and their symmetry-related counterparts. The perchlorate...

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Bibliographic Details
Main Authors: Viktor A. Tafeenko, Stanislav I. Gurskiy, Leonid A. Aslanov
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811027309
Description
Summary:In the title compound, [Cu(ClO4)2(CH3CN)2(H2O)2], the Cu2+ ion, located on a special position (site symmetry overline{1}), is coordinated by six monodentate ligands, viz. an N-coordinated acetonitrile, a perchlorate anion and a water molecule, and their symmetry-related counterparts. The perchlorate anion is disordered over two sets of sites with occupancies of 0.53 (2) and 0.47 (2). The crystal structure is stabilized by O—H...O hydrogen bonds involving the perchlorate ion and aqua H atoms.
ISSN:1600-5368

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