Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium

Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium

The electrochemical reduction of p-nitrobenzenesulfonyl chloride (NBSCl) in dimethylsulfoxide (DMSO) solution is used here as a model to investigate the role of sulfinic acid derivative in this compound’s global reduction process. Cyclic voltammetric experiments reveal the production of sulfinic aci...

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Main Authors: A. C .D. Angelo, S. M. A. Jorge, N. R. Stradiotto
Format: Article
Language:English
Published: Universidade Estadual Paulista 2018-05-01
Series:Eclética Química
Online Access:https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/471
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spelling doaj-1902f20cd00f40f082875108145e257e2020-11-25T00:24:20ZengUniversidade Estadual PaulistaEclética Química1678-46182018-05-01303576110.26850/1678-4618eqj.v30.3.2005.p57-61471Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic mediumA. C .D. Angelo0S. M. A. Jorge1N. R. Stradiotto2Dept. of Chemistry, F.C., UNESP, 17033-360, Bauru, SP, BrazilDept. of Chemistry and Biochemistry, I.B., UNESP, 18618-000, Botucatu, SP, BrazilDept. of Analytical Chemistry, I.Q., UNESP, 14040-910, Araraquara, SP, BrazilThe electrochemical reduction of p-nitrobenzenesulfonyl chloride (NBSCl) in dimethylsulfoxide (DMSO) solution is used here as a model to investigate the role of sulfinic acid derivative in this compound’s global reduction process. Cyclic voltammetric experiments reveal the production of sulfinic acid derivative, which is important in chemical reactions involving the original compound and other intermediates. This paper also discusses the probable mechanisms of the reduction.https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/471
collection DOAJ
language English
format Article
sources DOAJ
author A. C .D. Angelo
S. M. A. Jorge
N. R. Stradiotto
spellingShingle A. C .D. Angelo
S. M. A. Jorge
N. R. Stradiotto
Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium
Eclética Química
author_facet A. C .D. Angelo
S. M. A. Jorge
N. R. Stradiotto
author_sort A. C .D. Angelo
title Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium
title_short Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium
title_full Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium
title_fullStr Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium
title_full_unstemmed Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium
title_sort electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium
publisher Universidade Estadual Paulista
series Eclética Química
issn 1678-4618
publishDate 2018-05-01
description The electrochemical reduction of p-nitrobenzenesulfonyl chloride (NBSCl) in dimethylsulfoxide (DMSO) solution is used here as a model to investigate the role of sulfinic acid derivative in this compound’s global reduction process. Cyclic voltammetric experiments reveal the production of sulfinic acid derivative, which is important in chemical reactions involving the original compound and other intermediates. This paper also discusses the probable mechanisms of the reduction.
url https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/471
work_keys_str_mv AT acdangelo electrochemicalevidenceofsulfinicacidderivativeasanintermediateinthereductionofaromaticsulfonylchlorideinanaproticmedium
AT smajorge electrochemicalevidenceofsulfinicacidderivativeasanintermediateinthereductionofaromaticsulfonylchlorideinanaproticmedium
AT nrstradiotto electrochemicalevidenceofsulfinicacidderivativeasanintermediateinthereductionofaromaticsulfonylchlorideinanaproticmedium
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