Electrochemical selenium- and iodonium-initiated cyclisation of hydroxy-functionalised 1,4-dienes

Electrochemical selenium- and iodonium-initiated cyclisation of hydroxy-functionalised 1,4-dienes

The cobalt(I)-catalysed 1,4-hydrovinylation reaction of allyloxytrimethylsilane and allyl alcohol with substituted 1,3-dienes leads to hydroxy-functionalised 1,4-dienes in excellent regio- and diastereoselective fashion. Those 1,4-dienols can be converted into tetrahydrofuran and pyran derivatives u...

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Bibliographic Details
Main Authors: Philipp Röse, Steffen Emge, Jun-ichi Yoshida, Gerhard Hilt
Format: Article
Language:English
Published: Beilstein-Institut 2015-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
cyclic ethers
cyclisation
1,4-dienes
electrochemistry
iodonium
selenium
Online Access:https://doi.org/10.3762/bjoc.11.18

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