Bis(4-methylbenzylammonium) tetrabromidozincate

Bis(4-methylbenzylammonium) tetrabromidozincate

The structure of the non-centrosymmetric organic–inorganic hybrid material, (C8H12N)2[ZnBr4], consists of two 4-methylbenzylammonium cations and one [ZnBr4]2− anion connected by N—H...Br and C—H...Br hydrogen bonds. The ZnII cation has a slightly distorted tetrahedral coordination environment. No π–...

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Bibliographic Details
Main Authors: Ramkumar Aarthi, Aravazhi Amalan Thiruvalluvar, Chidambaram Ramachandra Raja
Format: Article
Language:English
Published: International Union of Crystallography 2018-05-01
Series:IUCrData
Subjects:
crystal structure
non-centrosymmetric organic-inorganic hybrid material
C—H...Br and N—H...Br hydrogen bondings
C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461800648X
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spelling doaj-188100e2554b4c599e06c397b7f082562020-11-25T00:38:32ZengInternational Union of CrystallographyIUCrData2414-31462018-05-0135x18064810.1107/S241431461800648Xwm4078Bis(4-methylbenzylammonium) tetrabromidozincateRamkumar Aarthi0Aravazhi Amalan Thiruvalluvar1Chidambaram Ramachandra Raja2Department of Physics, Government Arts College (Autonomous), Kumbakonam 612 002, Tamilnadu, IndiaPrincipal, Kunthavai Naacchiyaar Government Arts College for Women (Autonomous), Thanjavur 613 007, Tamilnadu, IndiaDepartment of Physics, Government Arts College (Autonomous), Kumbakonam 612 002, Tamilnadu, IndiaThe structure of the non-centrosymmetric organic–inorganic hybrid material, (C8H12N)2[ZnBr4], consists of two 4-methylbenzylammonium cations and one [ZnBr4]2− anion connected by N—H...Br and C—H...Br hydrogen bonds. The ZnII cation has a slightly distorted tetrahedral coordination environment. No π–π stacking interactions between the phenylene rings but C—H...π interactions towards them are observed. The structure was refined as a two-component inversion twin.http://scripts.iucr.org/cgi-bin/paper?S241431461800648Xcrystal structurenon-centrosymmetric organic-inorganic hybrid materialC—H...Br and N—H...Br hydrogen bondingsC—H...π interactions
collection DOAJ
language English
format Article
sources DOAJ
author Ramkumar Aarthi
Aravazhi Amalan Thiruvalluvar
Chidambaram Ramachandra Raja
spellingShingle Ramkumar Aarthi
Aravazhi Amalan Thiruvalluvar
Chidambaram Ramachandra Raja
Bis(4-methylbenzylammonium) tetrabromidozincate
IUCrData
crystal structure
non-centrosymmetric organic-inorganic hybrid material
C—H...Br and N—H...Br hydrogen bondings
C—H...π interactions
author_facet Ramkumar Aarthi
Aravazhi Amalan Thiruvalluvar
Chidambaram Ramachandra Raja
author_sort Ramkumar Aarthi
title Bis(4-methylbenzylammonium) tetrabromidozincate
title_short Bis(4-methylbenzylammonium) tetrabromidozincate
title_full Bis(4-methylbenzylammonium) tetrabromidozincate
title_fullStr Bis(4-methylbenzylammonium) tetrabromidozincate
title_full_unstemmed Bis(4-methylbenzylammonium) tetrabromidozincate
title_sort bis(4-methylbenzylammonium) tetrabromidozincate
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2018-05-01
description The structure of the non-centrosymmetric organic–inorganic hybrid material, (C8H12N)2[ZnBr4], consists of two 4-methylbenzylammonium cations and one [ZnBr4]2− anion connected by N—H...Br and C—H...Br hydrogen bonds. The ZnII cation has a slightly distorted tetrahedral coordination environment. No π–π stacking interactions between the phenylene rings but C—H...π interactions towards them are observed. The structure was refined as a two-component inversion twin.
topic crystal structure
non-centrosymmetric organic-inorganic hybrid material
C—H...Br and N—H...Br hydrogen bondings
C—H...π interactions
url http://scripts.iucr.org/cgi-bin/paper?S241431461800648X
work_keys_str_mv AT ramkumaraarthi bis4methylbenzylammoniumtetrabromidozincate
AT aravazhiamalanthiruvalluvar bis4methylbenzylammoniumtetrabromidozincate
AT chidambaramramachandraraja bis4methylbenzylammoniumtetrabromidozincate
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