Bis(4-methylbenzylammonium) tetrabromidozincate

Bis(4-methylbenzylammonium) tetrabromidozincate

The structure of the non-centrosymmetric organic–inorganic hybrid material, (C8H12N)2[ZnBr4], consists of two 4-methylbenzylammonium cations and one [ZnBr4]2− anion connected by N—H...Br and C—H...Br hydrogen bonds. The ZnII cation has a slightly distorted tetrahedral coordination environment. No π–...

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Bibliographic Details
Main Authors: Ramkumar Aarthi, Aravazhi Amalan Thiruvalluvar, Chidambaram Ramachandra Raja
Format: Article
Language:English
Published: International Union of Crystallography 2018-05-01
Series:IUCrData
Subjects:
crystal structure
non-centrosymmetric organic-inorganic hybrid material
C—H...Br and N—H...Br hydrogen bondings
C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461800648X
Description
Summary:The structure of the non-centrosymmetric organic–inorganic hybrid material, (C8H12N)2[ZnBr4], consists of two 4-methylbenzylammonium cations and one [ZnBr4]2− anion connected by N—H...Br and C—H...Br hydrogen bonds. The ZnII cation has a slightly distorted tetrahedral coordination environment. No π–π stacking interactions between the phenylene rings but C—H...π interactions towards them are observed. The structure was refined as a two-component inversion twin.
ISSN:2414-3146

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