Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate

Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate

The title compound, [SnI4(C25H22O2P2)]·CHCl3, crystallized from a chloroform solution of SnI4 and the diphosphine CH2(PPh2)2 exposed to air. The monomeric complex displays a distorted octahedral coordinaton for the tin(IV) atom with average Sn—I and Sn—O bond lengths of...

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Main Authors: Joseph M. Tanski, Allison M. Caldwell
Format: Article
Language:English
Published: International Union of Crystallography 2008-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808013627
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spelling doaj-186998ef975c4941b997ecc7dff84ecc2020-11-24T22:05:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-07-01647m894m89410.1107/S1600536808013627Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvateJoseph M. TanskiAllison M. CaldwellThe title compound, [SnI4(C25H22O2P2)]·CHCl3, crystallized from a chloroform solution of SnI4 and the diphosphine CH2(PPh2)2 exposed to air. The monomeric complex displays a distorted octahedral coordinaton for the tin(IV) atom with average Sn—I and Sn—O bond lengths of 2.79 (2) and 2.15 (1) Å, respectively.http://scripts.iucr.org/cgi-bin/paper?S1600536808013627
collection DOAJ
language English
format Article
sources DOAJ
author Joseph M. Tanski
Allison M. Caldwell
spellingShingle Joseph M. Tanski
Allison M. Caldwell
Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate
Acta Crystallographica Section E
author_facet Joseph M. Tanski
Allison M. Caldwell
author_sort Joseph M. Tanski
title Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate
title_short Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate
title_full Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate
title_fullStr Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate
title_full_unstemmed Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate
title_sort tetraiodido[methylenebis(diphenylphosphine oxide)-κ2o:o′]tin(iv) chloroform solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-07-01
description The title compound, [SnI4(C25H22O2P2)]·CHCl3, crystallized from a chloroform solution of SnI4 and the diphosphine CH2(PPh2)2 exposed to air. The monomeric complex displays a distorted octahedral coordinaton for the tin(IV) atom with average Sn—I and Sn—O bond lengths of 2.79 (2) and 2.15 (1) Å, respectively.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808013627
work_keys_str_mv AT josephmtanski tetraiodidomethylenebisdiphenylphosphineoxide9542oo8242tinivchloroformsolvate
AT allisonmcaldwell tetraiodidomethylenebisdiphenylphosphineoxide9542oo8242tinivchloroformsolvate
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