Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads

Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads

Amino acid interlinked pyrene and naphthalenediimide (NDI) based novel donor–acceptor–donor (D-A-D) triads are designed to exploit their topological symmetry and complementary π-character for facile charge-transfer complexation. Consequently, free-floating high-aspect-ratio supercoiled nanofibres an...

Full description

Bibliographic Details
Main Authors: M. B. Avinash, K. V. Sandeepa, T. Govindaraju
Format: Article
Language:English
Published: Beilstein-Institut 2013-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
amino acids
charge transfer
designer functional molecules
molecular assembly
molecular recognition
Online Access:https://doi.org/10.3762/bjoc.9.178
id doaj-185e0f1a240a4cb4852f209d9278aac7
record_format Article
spelling doaj-185e0f1a240a4cb4852f209d9278aac72021-02-02T08:25:23ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972013-08-01911565157110.3762/bjoc.9.1781860-5397-9-178Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triadsM. B. Avinash0K. V. Sandeepa1T. Govindaraju2Bioorganic Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064, India. Fax: +91 80 2208 2627; Tel: +91 80 2208 2969Bioorganic Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064, India. Fax: +91 80 2208 2627; Tel: +91 80 2208 2969Bioorganic Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064, India. Fax: +91 80 2208 2627; Tel: +91 80 2208 2969Amino acid interlinked pyrene and naphthalenediimide (NDI) based novel donor–acceptor–donor (D-A-D) triads are designed to exploit their topological symmetry and complementary π-character for facile charge-transfer complexation. Consequently, free-floating high-aspect-ratio supercoiled nanofibres and hierarchical helical bundles of triads are realized by modulating the chemical functionality of interlinking amino acids.https://doi.org/10.3762/bjoc.9.178amino acidscharge transferdesigner functional moleculesmolecular assemblymolecular recognition
collection DOAJ
language English
format Article
sources DOAJ
author M. B. Avinash
K. V. Sandeepa
T. Govindaraju
spellingShingle M. B. Avinash
K. V. Sandeepa
T. Govindaraju
Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
Beilstein Journal of Organic Chemistry
amino acids
charge transfer
designer functional molecules
molecular assembly
molecular recognition
author_facet M. B. Avinash
K. V. Sandeepa
T. Govindaraju
author_sort M. B. Avinash
title Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_short Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_full Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_fullStr Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_full_unstemmed Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_sort molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2013-08-01
description Amino acid interlinked pyrene and naphthalenediimide (NDI) based novel donor–acceptor–donor (D-A-D) triads are designed to exploit their topological symmetry and complementary π-character for facile charge-transfer complexation. Consequently, free-floating high-aspect-ratio supercoiled nanofibres and hierarchical helical bundles of triads are realized by modulating the chemical functionality of interlinking amino acids.
topic amino acids
charge transfer
designer functional molecules
molecular assembly
molecular recognition
url https://doi.org/10.3762/bjoc.9.178
work_keys_str_mv AT mbavinash molecularassemblyofaminoacidinterlinkedtopologicallysymmetricpcomplementarydonoracceptordonortriads
AT kvsandeepa molecularassemblyofaminoacidinterlinkedtopologicallysymmetricpcomplementarydonoracceptordonortriads
AT tgovindaraju molecularassemblyofaminoacidinterlinkedtopologicallysymmetricpcomplementarydonoracceptordonortriads
_version_ 1724297112281153536

Similar Items