Efficient Direct Nitrosylation of α-Diimine Rhenium Tricarbonyl Complexes to Structurally Nearly Identical Higher Charge Congeners Activable towards Photo-CO Release

Efficient Direct Nitrosylation of α-Diimine Rhenium Tricarbonyl Complexes to Structurally Nearly Identical Higher Charge Congeners Activable towards Photo-CO Release

The reaction of rhenium α-diimine (N-N) tricarbonyl complexes with nitrosonium tetrafluoroborate yields the corresponding dicarbonyl-nitrosyl [Re(CO)<sub>2</sub>(NO)(N-N)X]<sup>+</sup> species (where X = halide). The complexes, accessible in a single step in good yield, are s...

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Bibliographic Details
Main Authors: Sara Nasiri Sovari, Isabelle Kolly, Kevin Schindler, Youri Cortat, Shing-Chi Liu, Aurelien Crochet, Aleksandar Pavic, Fabio Zobi
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Molecules
Subjects:
rhenium
dicarbonyl
nitrosyl
photoCORM
Online Access:https://www.mdpi.com/1420-3049/26/17/5302

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