Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to Octahedra

Growth of Cu polyhedral structures with well-defined and controllable shapes faced tremendous synthetic challenges in colloid nanocrystal synthesis in the past few decades. In this article, we report a facile approach for the synthesis of Cu nanocrystals with systematic morphological evolution. Tran...

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Main Authors: Kuan-Ting Chen, Wei-Chung Chang, Shu-Chen Lu, Po-Yuan Yang, Hsing-Yu Tuan
Format: Article
Language:English
Published: Hindawi Limited 2019-01-01
Series:Journal of Nanomaterials
Online Access:http://dx.doi.org/10.1155/2019/2890162
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spelling doaj-1791a6dee122400da6278f94e5aa6fdd2020-11-25T02:13:31ZengHindawi LimitedJournal of Nanomaterials1687-41101687-41292019-01-01201910.1155/2019/28901622890162Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to OctahedraKuan-Ting Chen0Wei-Chung Chang1Shu-Chen Lu2Po-Yuan Yang3Hsing-Yu Tuan4Department of Chemical Engineering, National Tsing Hua University, Hsinchu, 300, TaiwanDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300, TaiwanDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300, TaiwanDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300, TaiwanDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300, TaiwanGrowth of Cu polyhedral structures with well-defined and controllable shapes faced tremendous synthetic challenges in colloid nanocrystal synthesis in the past few decades. In this article, we report a facile approach for the synthesis of Cu nanocrystals with systematic morphological evolution. Transitional truncated octahedral, edge- and corner-truncated octahedral, all-corner-truncated octahedral, and octahedral structures were obtained in a solution-based reduction reaction by precise tuning reaction time. Four distinct morphologies of nanocrystals have been characterized by SEM technique. The optical properties of these various morphologies of nanocrystals were also investigated, and it indicates that the SPR band shifts red while the shape of nanoparticles evolves from transitional truncated octahedral to octahedral, whose resonant bands are transferred from 590 nm to 620 nm.http://dx.doi.org/10.1155/2019/2890162
collection DOAJ
language English
format Article
sources DOAJ
author Kuan-Ting Chen
Wei-Chung Chang
Shu-Chen Lu
Po-Yuan Yang
Hsing-Yu Tuan
spellingShingle Kuan-Ting Chen
Wei-Chung Chang
Shu-Chen Lu
Po-Yuan Yang
Hsing-Yu Tuan
Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to Octahedra
Journal of Nanomaterials
author_facet Kuan-Ting Chen
Wei-Chung Chang
Shu-Chen Lu
Po-Yuan Yang
Hsing-Yu Tuan
author_sort Kuan-Ting Chen
title Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to Octahedra
title_short Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to Octahedra
title_full Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to Octahedra
title_fullStr Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to Octahedra
title_full_unstemmed Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to Octahedra
title_sort facile synthesis of cu nanocrystals with morphology evolution from transitional truncated octahedra to octahedra
publisher Hindawi Limited
series Journal of Nanomaterials
issn 1687-4110
1687-4129
publishDate 2019-01-01
description Growth of Cu polyhedral structures with well-defined and controllable shapes faced tremendous synthetic challenges in colloid nanocrystal synthesis in the past few decades. In this article, we report a facile approach for the synthesis of Cu nanocrystals with systematic morphological evolution. Transitional truncated octahedral, edge- and corner-truncated octahedral, all-corner-truncated octahedral, and octahedral structures were obtained in a solution-based reduction reaction by precise tuning reaction time. Four distinct morphologies of nanocrystals have been characterized by SEM technique. The optical properties of these various morphologies of nanocrystals were also investigated, and it indicates that the SPR band shifts red while the shape of nanoparticles evolves from transitional truncated octahedral to octahedral, whose resonant bands are transferred from 590 nm to 620 nm.
url http://dx.doi.org/10.1155/2019/2890162
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