Crystal structure of N,N′-bis(diisopropylphosphanyl)-4-methylpyridine-2,6-diamine

Crystal structure of N,N′-bis(diisopropylphosphanyl)-4-methylpyridine-2,6-diamine

In the molecule of the title compound, C18H35N3P2, the methylpyridine-2,6-diamine moiety is almost planar, with a maximum deviation of 0.0129 (9) Å for one of the amine N atoms. Whereas one of the P atoms is co-planar with this mean plane [deviation = 0.0158 (10) Å], the other P atom is considerably...

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Bibliographic Details
Main Authors: Berthold Stöger, Matthias Weil, Bernhard Bichler, Wolfgang Eder, Karl Kirchner
Format: Article
Language:English
Published: International Union of Crystallography 2014-09-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
PNP pincer ligand
methylpyridine-2,6-diamine
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814010976
Description
Summary:In the molecule of the title compound, C18H35N3P2, the methylpyridine-2,6-diamine moiety is almost planar, with a maximum deviation of 0.0129 (9) Å for one of the amine N atoms. Whereas one of the P atoms is co-planar with this mean plane [deviation = 0.0158 (10) Å], the other P atom is considerably displaced out of the mean plane by 0.5882 (10) Å. In the crystal, no directional intermolecular interactions beyond van der Waals contacts could be identified.
ISSN:1600-5368

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