(9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate

(9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate

The title compound, C29H35NO6.0.334C3H8O, a novel chiral N-(fluoren-9-ylmethyloxyxcarbonyl) precursor, crystallizes with two independent carbamate (M) molecules and propan-2-ol solvent molecules in the unit cell. Its crystal structure has been determined from barely adequate data obtained from a mul...

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Main Authors: Graeme J. Gainsford, Andreas Luxenburger
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811055139
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spelling doaj-16e4f510f7ae452b87737a9a67e1fbaa2020-11-24T21:52:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682o403o40410.1107/S1600536811055139(9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvateGraeme J. GainsfordAndreas LuxenburgerThe title compound, C29H35NO6.0.334C3H8O, a novel chiral N-(fluoren-9-ylmethyloxyxcarbonyl) precursor, crystallizes with two independent carbamate (M) molecules and propan-2-ol solvent molecules in the unit cell. Its crystal structure has been determined from barely adequate data obtained from a multi-fragment needle crystal. In the crystal, N—H...O hydrogen bonds link M molecules related by translation along the a axis into two independent chains. The ordered solvent molecule, having a partial occupancy of 0.334, is attached to one independent M molecule through O—H...O hydrogen bonds. The crystal packing exhibits weak intermolecular C—H...O interactions and voids of 270 Å3 filled with randomly disordered solvent molecules which were handled using the SQUEEZE methodology.http://scripts.iucr.org/cgi-bin/paper?S1600536811055139
collection DOAJ
language English
format Article
sources DOAJ
author Graeme J. Gainsford
Andreas Luxenburger
spellingShingle Graeme J. Gainsford
Andreas Luxenburger
(9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate
Acta Crystallographica Section E
author_facet Graeme J. Gainsford
Andreas Luxenburger
author_sort Graeme J. Gainsford
title (9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate
title_short (9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate
title_full (9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate
title_fullStr (9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate
title_full_unstemmed (9H-Fluoren-9-yl)methyl N-{(2R,3R,4S)-4-hydroxy-2-[(2S,5R)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate
title_sort (9h-fluoren-9-yl)methyl n-{(2r,3r,4s)-4-hydroxy-2-[(2s,5r)-2-isopropyl-5-methylcyclohexyloxy]-5-oxooxolan-3-yl}carbamate propan-2-ol 0.334-solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description The title compound, C29H35NO6.0.334C3H8O, a novel chiral N-(fluoren-9-ylmethyloxyxcarbonyl) precursor, crystallizes with two independent carbamate (M) molecules and propan-2-ol solvent molecules in the unit cell. Its crystal structure has been determined from barely adequate data obtained from a multi-fragment needle crystal. In the crystal, N—H...O hydrogen bonds link M molecules related by translation along the a axis into two independent chains. The ordered solvent molecule, having a partial occupancy of 0.334, is attached to one independent M molecule through O—H...O hydrogen bonds. The crystal packing exhibits weak intermolecular C—H...O interactions and voids of 270 Å3 filled with randomly disordered solvent molecules which were handled using the SQUEEZE methodology.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811055139
work_keys_str_mv AT graemejgainsford 9hfluoren9ylmethyln2r3r4s4hydroxy22s5r2isopropyl5methylcyclohexyloxy5oxooxolan3ylcarbamatepropan2ol0334solvate
AT andreasluxenburger 9hfluoren9ylmethyln2r3r4s4hydroxy22s5r2isopropyl5methylcyclohexyloxy5oxooxolan3ylcarbamatepropan2ol0334solvate
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