Synthesis and Characterization of a Sulfonyl- and Iminophosphoryl-Functionalized Methanide and Methandiide
The synthesis of [H2C(PPh2=NSiMe3)(SO2Ph)] (1) and its mono- and dimetalation are reported. Due to the strong anion-stabilizing abilities of the iminophosphoryl and the sulfonyl group monometalation to 1-K and dimetalation to 1-Li2 proceed smoothly with potassium hydride and methyllithium, respectiv...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2016-12-01
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| Series: | Inorganics |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2304-6740/4/4/40 |