Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate

Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate

In the title compound, [Fe(C5H5)(C21H20NO5)], the pyrrolidine and cyclopentanone rings exhibit a twist conformation. The pyrrolidine ring is almost perpendicular to the cyclopentanone ring, making a dihedral angle of 81.91 (6)°. The molecular conformation is stabilized by...

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Main Authors: E. Theboral Sugi Kamala, S. Nirmala, L. Sudha, S. Kathiravan, R. Raghunathan
Format: Article
Language:English
Published: International Union of Crystallography 2009-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809018583
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spelling doaj-16a03262c11840aeade65a0950657c392020-11-25T01:38:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656m687m68810.1107/S1600536809018583Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylateE. Theboral Sugi KamalaS. NirmalaL. SudhaS. KathiravanR. RaghunathanIn the title compound, [Fe(C5H5)(C21H20NO5)], the pyrrolidine and cyclopentanone rings exhibit a twist conformation. The pyrrolidine ring is almost perpendicular to the cyclopentanone ring, making a dihedral angle of 81.91 (6)°. The molecular conformation is stabilized by an intramolecular O—H...N hydrogen bond and C—H...O interactions. The crystal structure is stabilized by intermolecular C—H...O interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536809018583
collection DOAJ
language English
format Article
sources DOAJ
author E. Theboral Sugi Kamala
S. Nirmala
L. Sudha
S. Kathiravan
R. Raghunathan
spellingShingle E. Theboral Sugi Kamala
S. Nirmala
L. Sudha
S. Kathiravan
R. Raghunathan
Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate
Acta Crystallographica Section E
author_facet E. Theboral Sugi Kamala
S. Nirmala
L. Sudha
S. Kathiravan
R. Raghunathan
author_sort E. Theboral Sugi Kamala
title Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate
title_short Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate
title_full Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate
title_fullStr Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate
title_full_unstemmed Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate
title_sort methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1h-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-06-01
description In the title compound, [Fe(C5H5)(C21H20NO5)], the pyrrolidine and cyclopentanone rings exhibit a twist conformation. The pyrrolidine ring is almost perpendicular to the cyclopentanone ring, making a dihedral angle of 81.91 (6)°. The molecular conformation is stabilized by an intramolecular O—H...N hydrogen bond and C—H...O interactions. The crystal structure is stabilized by intermolecular C—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809018583
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AT snirmala methyl5ferrocenyl5ahydroxy1methyl10oxo233a45a10hexahydro1hindeno122amp82423amp8242furo3amp82424amp8242bpyrrole3acarboxylate
AT lsudha methyl5ferrocenyl5ahydroxy1methyl10oxo233a45a10hexahydro1hindeno122amp82423amp8242furo3amp82424amp8242bpyrrole3acarboxylate
AT skathiravan methyl5ferrocenyl5ahydroxy1methyl10oxo233a45a10hexahydro1hindeno122amp82423amp8242furo3amp82424amp8242bpyrrole3acarboxylate
AT rraghunathan methyl5ferrocenyl5ahydroxy1methyl10oxo233a45a10hexahydro1hindeno122amp82423amp8242furo3amp82424amp8242bpyrrole3acarboxylate
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