catena-Poly[[bis(μ2-4-aminobenzenesulfonato-κ2O:O)disilver]-bis(μ2-4,4′-bipyridine-κ2N:N′)]

catena-Poly[[bis(μ2-4-aminobenzenesulfonato-κ2O:O)disilver]-bis(μ2-4,4′-bipyridine-κ2N:N′)]

In the title compound, [Ag2(C6H6NO3S)2(C10H8N2)2]n, the AgI atom is four-coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) and two O atoms from two independent 4-aminobenzenesulfonate (ABS) ligands. The two inter-chain AgI atoms are bridged by two independent ABS...

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Bibliographic Details
Main Authors: Yong-Qiang Dai, Xian-You Yuan, Min Zhang, Guang-Chuan Ou
Format: Article
Language:English
Published: International Union of Crystallography 2008-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680803804X
Description
Summary:In the title compound, [Ag2(C6H6NO3S)2(C10H8N2)2]n, the AgI atom is four-coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) and two O atoms from two independent 4-aminobenzenesulfonate (ABS) ligands. The two inter-chain AgI atoms are bridged by two independent ABS ligands through weak Ag—O bonds and Ag...Ag attractions, forming a ladder-like chain coordination polymer [Ag2(ABS)2(bipy)2]n parallel to [001], which is further linked to generate a two-dimensional structure via N—H...O hydrogen-bonding interactions.
ISSN:1600-5368

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