Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate

Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate

In the title compound, C29H26N2O5S, the piperidine ring adopts a half-chair conformation. The phenyl rings are oriented at dihedral angles of 75.76 (12) and 86.64 (9)° with respect to the best plane through the piperidine ring. The dihedral angle between the...

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Main Authors: G. Aridoss, S. Sundaramoorthy, D. Velmurugan, Y. T. Jeong
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811022744
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spelling doaj-155087e51fcb435693aa69e89ffd6f392020-11-25T00:52:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677o1731o173110.1107/S1600536811022744Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylateG. AridossS. SundaramoorthyD. VelmuruganY. T. JeongIn the title compound, C29H26N2O5S, the piperidine ring adopts a half-chair conformation. The phenyl rings are oriented at dihedral angles of 75.76 (12) and 86.64 (9)° with respect to the best plane through the piperidine ring. The dihedral angle between the two phenyl rings is 30.81 (13)°. The benzoxazole ring system is approximately planar [maximum deviation = 0.016 (4) Å]. The atoms of the ethyl side chain are disordered over two sets of sites [site occupancies = 0.376 (9) and 0.624 (9)]. The molecular conformation is stabilized by an intramolecular O—H...O hydrogen bond, generating an S(6) motif. The crystal packing is stabilized by intermolecular C—H...O interactions, generating a chain running along the a axis.http://scripts.iucr.org/cgi-bin/paper?S1600536811022744
collection DOAJ
language English
format Article
sources DOAJ
author G. Aridoss
S. Sundaramoorthy
D. Velmurugan
Y. T. Jeong
spellingShingle G. Aridoss
S. Sundaramoorthy
D. Velmurugan
Y. T. Jeong
Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate
Acta Crystallographica Section E
author_facet G. Aridoss
S. Sundaramoorthy
D. Velmurugan
Y. T. Jeong
author_sort G. Aridoss
title Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate
title_short Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate
title_full Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate
title_fullStr Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate
title_full_unstemmed Ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate
title_sort ethyl 1-[2-(1,3-benzoxazol-2-ylsulfanyl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description In the title compound, C29H26N2O5S, the piperidine ring adopts a half-chair conformation. The phenyl rings are oriented at dihedral angles of 75.76 (12) and 86.64 (9)° with respect to the best plane through the piperidine ring. The dihedral angle between the two phenyl rings is 30.81 (13)°. The benzoxazole ring system is approximately planar [maximum deviation = 0.016 (4) Å]. The atoms of the ethyl side chain are disordered over two sets of sites [site occupancies = 0.376 (9) and 0.624 (9)]. The molecular conformation is stabilized by an intramolecular O—H...O hydrogen bond, generating an S(6) motif. The crystal packing is stabilized by intermolecular C—H...O interactions, generating a chain running along the a axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811022744
work_keys_str_mv AT garidoss ethyl1213benzoxazol2ylsulfanylacetyl4hydroxy26diphenyl1256tetrahydropyridine3carboxylate
AT ssundaramoorthy ethyl1213benzoxazol2ylsulfanylacetyl4hydroxy26diphenyl1256tetrahydropyridine3carboxylate
AT dvelmurugan ethyl1213benzoxazol2ylsulfanylacetyl4hydroxy26diphenyl1256tetrahydropyridine3carboxylate
AT ytjeong ethyl1213benzoxazol2ylsulfanylacetyl4hydroxy26diphenyl1256tetrahydropyridine3carboxylate
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