Analysis of the chemical equilibrium of combustion at constant volume

Determining the composition of a mixture of combustion gases at a given temperature is based on chemical equilibrium, when the equilibrium constants are calculated on the assumption of constant pressure and temperature. In this paper, an analysis of changes occurring when combustion takes place at...

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Main Author: Marius BREBENEL
Format: Article
Language:English
Published: National Institute for Aerospace Research “Elie Carafoli” - INCAS 2014-04-01
Series:INCAS Bulletin
Subjects:
Online Access:http://bulletin.incas.ro/files/brebenel_m__vol_6_spec_iss_1.pdf
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spelling doaj-154fbacdac8046d694a58e128636c2c62020-11-24T21:57:27ZengNational Institute for Aerospace Research “Elie Carafoli” - INCASINCAS Bulletin2066-82012247-45282014-04-016Special 1253410.13111/2066-8201.2014.6.S1.3Analysis of the chemical equilibrium of combustion at constant volumeMarius BREBENEL0“POLITEHNICA” University of Bucharest, Faculty of Aerospace Engineering Gh. Polizu Street 1-5, 011061, Bucharest, Romania mariusbreb@yahoo.comDetermining the composition of a mixture of combustion gases at a given temperature is based on chemical equilibrium, when the equilibrium constants are calculated on the assumption of constant pressure and temperature. In this paper, an analysis of changes occurring when combustion takes place at constant volume is presented, deriving a specific formula of the equilibrium constant. The simple reaction of carbon combustion in pure oxygen in both cases (constant pressure and constant volume) is next considered as example of application, observing the changes occurring in the composition of the combustion gases depending on temperature.http://bulletin.incas.ro/files/brebenel_m__vol_6_spec_iss_1.pdfmathematical modelingcombustionchemical equilibriumthermodynamic properties
collection DOAJ
language English
format Article
sources DOAJ
author Marius BREBENEL
spellingShingle Marius BREBENEL
Analysis of the chemical equilibrium of combustion at constant volume
INCAS Bulletin
mathematical modeling
combustion
chemical equilibrium
thermodynamic properties
author_facet Marius BREBENEL
author_sort Marius BREBENEL
title Analysis of the chemical equilibrium of combustion at constant volume
title_short Analysis of the chemical equilibrium of combustion at constant volume
title_full Analysis of the chemical equilibrium of combustion at constant volume
title_fullStr Analysis of the chemical equilibrium of combustion at constant volume
title_full_unstemmed Analysis of the chemical equilibrium of combustion at constant volume
title_sort analysis of the chemical equilibrium of combustion at constant volume
publisher National Institute for Aerospace Research “Elie Carafoli” - INCAS
series INCAS Bulletin
issn 2066-8201
2247-4528
publishDate 2014-04-01
description Determining the composition of a mixture of combustion gases at a given temperature is based on chemical equilibrium, when the equilibrium constants are calculated on the assumption of constant pressure and temperature. In this paper, an analysis of changes occurring when combustion takes place at constant volume is presented, deriving a specific formula of the equilibrium constant. The simple reaction of carbon combustion in pure oxygen in both cases (constant pressure and constant volume) is next considered as example of application, observing the changes occurring in the composition of the combustion gases depending on temperature.
topic mathematical modeling
combustion
chemical equilibrium
thermodynamic properties
url http://bulletin.incas.ro/files/brebenel_m__vol_6_spec_iss_1.pdf
work_keys_str_mv AT mariusbrebenel analysisofthechemicalequilibriumofcombustionatconstantvolume
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