catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ2O,O′]cadmium(II)}]-di-μ2-thiocyanato-κ2N:S;κ2S:N]
The asymmetric unit of the title compound, [Cd2Cl2(NCS)2(C15H15NO2)2]n, contains the Schiff base 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) ligand, one thiocyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thiocyanate and...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808038099 |
| Summary: | The asymmetric unit of the title compound, [Cd2Cl2(NCS)2(C15H15NO2)2]n, contains the Schiff base 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) ligand, one thiocyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thiocyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The CdII coordination environment contains two Cl atoms, one thiocyanate (SCN) S atom, one isothiocyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation. |
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| ISSN: | 1600-5368 |