Bis(1,3-dibutylthiourea)dicyanidomercury(II)

Bis(1,3-dibutylthiourea)dicyanidomercury(II)

In the title compound, [Hg(CN)2(C9H20N2S)2], the Hg atom lies on a twofold rotation axis. There is only half a molecule in the asymmetric unit. The Hg atom has a distorted tetrahedral coordination involving the S atoms of two 1-butyl-3-propylthiourea groups and the C atoms of the two CN&#872...

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Main Authors: Saeed Ahmad, Haseeba Sadaf, Mehmet Akkurt, Shahzad Sharif, Islam Ullah Khan
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809035594
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spelling doaj-151211157e28477faeccc9f7a5e6fec62020-11-24T22:15:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510m1191m119210.1107/S1600536809035594Bis(1,3-dibutylthiourea)dicyanidomercury(II)Saeed AhmadHaseeba SadafMehmet AkkurtShahzad SharifIslam Ullah KhanIn the title compound, [Hg(CN)2(C9H20N2S)2], the Hg atom lies on a twofold rotation axis. There is only half a molecule in the asymmetric unit. The Hg atom has a distorted tetrahedral coordination involving the S atoms of two 1-butyl-3-propylthiourea groups and the C atoms of the two CN− anions. In the crystal packing, adjacent molecules are connected by intermolecular N—H...N and N—H...S hydrogen bonds, forming infinite chains in three dimensions. http://scripts.iucr.org/cgi-bin/paper?S1600536809035594
collection DOAJ
language English
format Article
sources DOAJ
author Saeed Ahmad
Haseeba Sadaf
Mehmet Akkurt
Shahzad Sharif
Islam Ullah Khan
spellingShingle Saeed Ahmad
Haseeba Sadaf
Mehmet Akkurt
Shahzad Sharif
Islam Ullah Khan
Bis(1,3-dibutylthiourea)dicyanidomercury(II)
Acta Crystallographica Section E
author_facet Saeed Ahmad
Haseeba Sadaf
Mehmet Akkurt
Shahzad Sharif
Islam Ullah Khan
author_sort Saeed Ahmad
title Bis(1,3-dibutylthiourea)dicyanidomercury(II)
title_short Bis(1,3-dibutylthiourea)dicyanidomercury(II)
title_full Bis(1,3-dibutylthiourea)dicyanidomercury(II)
title_fullStr Bis(1,3-dibutylthiourea)dicyanidomercury(II)
title_full_unstemmed Bis(1,3-dibutylthiourea)dicyanidomercury(II)
title_sort bis(1,3-dibutylthiourea)dicyanidomercury(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-10-01
description In the title compound, [Hg(CN)2(C9H20N2S)2], the Hg atom lies on a twofold rotation axis. There is only half a molecule in the asymmetric unit. The Hg atom has a distorted tetrahedral coordination involving the S atoms of two 1-butyl-3-propylthiourea groups and the C atoms of the two CN− anions. In the crystal packing, adjacent molecules are connected by intermolecular N—H...N and N—H...S hydrogen bonds, forming infinite chains in three dimensions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809035594
work_keys_str_mv AT saeedahmad bis13dibutylthioureadicyanidomercuryii
AT haseebasadaf bis13dibutylthioureadicyanidomercuryii
AT mehmetakkurt bis13dibutylthioureadicyanidomercuryii
AT shahzadsharif bis13dibutylthioureadicyanidomercuryii
AT islamullahkhan bis13dibutylthioureadicyanidomercuryii
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