Bis(1,3-dibutylthiourea)dicyanidomercury(II)

Bis(1,3-dibutylthiourea)dicyanidomercury(II)

In the title compound, [Hg(CN)2(C9H20N2S)2], the Hg atom lies on a twofold rotation axis. There is only half a molecule in the asymmetric unit. The Hg atom has a distorted tetrahedral coordination involving the S atoms of two 1-butyl-3-propylthiourea groups and the C atoms of the two CN&#872...

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Bibliographic Details
Main Authors: Saeed Ahmad, Haseeba Sadaf, Mehmet Akkurt, Shahzad Sharif, Islam Ullah Khan
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809035594
Description
Summary:In the title compound, [Hg(CN)2(C9H20N2S)2], the Hg atom lies on a twofold rotation axis. There is only half a molecule in the asymmetric unit. The Hg atom has a distorted tetrahedral coordination involving the S atoms of two 1-butyl-3-propylthiourea groups and the C atoms of the two CN− anions. In the crystal packing, adjacent molecules are connected by intermolecular N—H...N and N—H...S hydrogen bonds, forming infinite chains in three dimensions.
ISSN:1600-5368

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