Di-μ-iodido-bis{[(R)-(+)-2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]copper(I)} 0.67-hydrate

• Main Authors: Daniel Volz, Martin Nieger, Stefan Bräse
• Format: Article
• Language: English
• Published: International Union of Crystallography 2012-04-01
• Series: Acta Crystallographica Section E
• Online Access: http://scripts.iucr.org/cgi-bin/paper?S1600536812011051

The structure of the title compound, [Cu2I2(C44H32P2)2]·0.67H2O, has been determined because of its interesting catalytic and optical features. The molecule, which has non-crystallographic C2-symmetry, consists of a core structure of two CuI ions, bridged by two iodide ions. Each CuI ion is also coordinated by one equivalent of the chiral bidentate (R)-BINAP ligand [BINAP = 2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl]. Thus, both cations show a distorted tetrahedral geometry being surrounded by two I atoms and two P atoms from the (R)-BINAP ligands. The complex consists of isolated butterfly-shaped molecules featuring an angle of 146.11 (2)° between adjacent CuI2 planes. The structure displays intramolecular C—H...I hydrogen bonding and contains disordered water. The absolute configuration of this chiral complex was determined by anomalous dispersion effects.