The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore

Sodium silicate (SS) has been widely used as a depressant for the scheelite flotation. However, low selectivity and large amount of SS remains a tough problem. In this work, the effect of depressant sesbania gum (SGM) on the flotation of a talc-containing scheelite ore was investigated through pure...

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Main Authors: Kaile Zhao, Guohua Gu, Xiaohui Wang, Wu Yan, YeHuai Hu
Format: Article
Language:English
Published: Elsevier 2019-01-01
Series:Journal of Materials Research and Technology
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785417304933
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spelling doaj-149d9308697b45f29b2a23a6458c1c502020-11-25T01:25:22ZengElsevierJournal of Materials Research and Technology2238-78542019-01-01811421The effect of depressant sesbania gum on the flotation of a talc-containing scheelite oreKaile Zhao0Guohua Gu1Xiaohui Wang2Wu Yan3YeHuai Hu4School of Minerals Processing and Bio-engineering, Central South University, Changsha, China; Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, China; Corresponding authors.School of Minerals Processing and Bio-engineering, Central South University, Changsha, China; Corresponding authors.Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, ChinaInstitute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, ChinaSchool of Minerals Processing and Bio-engineering, Central South University, Changsha, ChinaSodium silicate (SS) has been widely used as a depressant for the scheelite flotation. However, low selectivity and large amount of SS remains a tough problem. In this work, the effect of depressant sesbania gum (SGM) on the flotation of a talc-containing scheelite ore was investigated through pure mineral flotation and run-of-mine ore flotation tests. The flotation tests showed that the selective separation between scheelite and talc was achieved using a new reagent schedule, i.e., a lower dosage of SGM (80 mg/L) and a new collector of sulfonated oleic acid (SNaOL, 40 mol/L) at pH 9.0. A concentrate with WO3 grade of 52.0% and recovery of 78.4% was achieved by the run-of-mine ore batch flotation test. In addition, the mechanism of the selective separation was investigated by zeta-potential measurements, FTIR spectra and XPS analyses, which demonstrated that SNaOL absorbed more strongly and selectively on the “scheelite + SGM” surface than on the “talc + SGM” surface, while SGM could more selectively interact on the talc surface than on the scheelite surface. SGM absorbed on the talc surface by chemical adsorption between the Mg/Si atom of the talc surface and OH group in SGM molecule. Keywords: Scheelite, Talc, Sesbania gum, Sulfonated oleic acid, Adsorption mechanismhttp://www.sciencedirect.com/science/article/pii/S2238785417304933
collection DOAJ
language English
format Article
sources DOAJ
author Kaile Zhao
Guohua Gu
Xiaohui Wang
Wu Yan
YeHuai Hu
spellingShingle Kaile Zhao
Guohua Gu
Xiaohui Wang
Wu Yan
YeHuai Hu
The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore
Journal of Materials Research and Technology
author_facet Kaile Zhao
Guohua Gu
Xiaohui Wang
Wu Yan
YeHuai Hu
author_sort Kaile Zhao
title The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore
title_short The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore
title_full The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore
title_fullStr The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore
title_full_unstemmed The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore
title_sort effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore
publisher Elsevier
series Journal of Materials Research and Technology
issn 2238-7854
publishDate 2019-01-01
description Sodium silicate (SS) has been widely used as a depressant for the scheelite flotation. However, low selectivity and large amount of SS remains a tough problem. In this work, the effect of depressant sesbania gum (SGM) on the flotation of a talc-containing scheelite ore was investigated through pure mineral flotation and run-of-mine ore flotation tests. The flotation tests showed that the selective separation between scheelite and talc was achieved using a new reagent schedule, i.e., a lower dosage of SGM (80 mg/L) and a new collector of sulfonated oleic acid (SNaOL, 40 mol/L) at pH 9.0. A concentrate with WO3 grade of 52.0% and recovery of 78.4% was achieved by the run-of-mine ore batch flotation test. In addition, the mechanism of the selective separation was investigated by zeta-potential measurements, FTIR spectra and XPS analyses, which demonstrated that SNaOL absorbed more strongly and selectively on the “scheelite + SGM” surface than on the “talc + SGM” surface, while SGM could more selectively interact on the talc surface than on the scheelite surface. SGM absorbed on the talc surface by chemical adsorption between the Mg/Si atom of the talc surface and OH group in SGM molecule. Keywords: Scheelite, Talc, Sesbania gum, Sulfonated oleic acid, Adsorption mechanism
url http://www.sciencedirect.com/science/article/pii/S2238785417304933
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