The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore
Sodium silicate (SS) has been widely used as a depressant for the scheelite flotation. However, low selectivity and large amount of SS remains a tough problem. In this work, the effect of depressant sesbania gum (SGM) on the flotation of a talc-containing scheelite ore was investigated through pure...
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doaj-149d9308697b45f29b2a23a6458c1c502020-11-25T01:25:22ZengElsevierJournal of Materials Research and Technology2238-78542019-01-01811421The effect of depressant sesbania gum on the flotation of a talc-containing scheelite oreKaile Zhao0Guohua Gu1Xiaohui Wang2Wu Yan3YeHuai Hu4School of Minerals Processing and Bio-engineering, Central South University, Changsha, China; Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, China; Corresponding authors.School of Minerals Processing and Bio-engineering, Central South University, Changsha, China; Corresponding authors.Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, ChinaInstitute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, ChinaSchool of Minerals Processing and Bio-engineering, Central South University, Changsha, ChinaSodium silicate (SS) has been widely used as a depressant for the scheelite flotation. However, low selectivity and large amount of SS remains a tough problem. In this work, the effect of depressant sesbania gum (SGM) on the flotation of a talc-containing scheelite ore was investigated through pure mineral flotation and run-of-mine ore flotation tests. The flotation tests showed that the selective separation between scheelite and talc was achieved using a new reagent schedule, i.e., a lower dosage of SGM (80 mg/L) and a new collector of sulfonated oleic acid (SNaOL, 40 mol/L) at pH 9.0. A concentrate with WO3 grade of 52.0% and recovery of 78.4% was achieved by the run-of-mine ore batch flotation test. In addition, the mechanism of the selective separation was investigated by zeta-potential measurements, FTIR spectra and XPS analyses, which demonstrated that SNaOL absorbed more strongly and selectively on the “scheelite + SGM” surface than on the “talc + SGM” surface, while SGM could more selectively interact on the talc surface than on the scheelite surface. SGM absorbed on the talc surface by chemical adsorption between the Mg/Si atom of the talc surface and OH group in SGM molecule. Keywords: Scheelite, Talc, Sesbania gum, Sulfonated oleic acid, Adsorption mechanismhttp://www.sciencedirect.com/science/article/pii/S2238785417304933 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kaile Zhao Guohua Gu Xiaohui Wang Wu Yan YeHuai Hu |
spellingShingle |
Kaile Zhao Guohua Gu Xiaohui Wang Wu Yan YeHuai Hu The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore Journal of Materials Research and Technology |
author_facet |
Kaile Zhao Guohua Gu Xiaohui Wang Wu Yan YeHuai Hu |
author_sort |
Kaile Zhao |
title |
The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore |
title_short |
The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore |
title_full |
The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore |
title_fullStr |
The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore |
title_full_unstemmed |
The effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore |
title_sort |
effect of depressant sesbania gum on the flotation of a talc-containing scheelite ore |
publisher |
Elsevier |
series |
Journal of Materials Research and Technology |
issn |
2238-7854 |
publishDate |
2019-01-01 |
description |
Sodium silicate (SS) has been widely used as a depressant for the scheelite flotation. However, low selectivity and large amount of SS remains a tough problem. In this work, the effect of depressant sesbania gum (SGM) on the flotation of a talc-containing scheelite ore was investigated through pure mineral flotation and run-of-mine ore flotation tests. The flotation tests showed that the selective separation between scheelite and talc was achieved using a new reagent schedule, i.e., a lower dosage of SGM (80 mg/L) and a new collector of sulfonated oleic acid (SNaOL, 40 mol/L) at pH 9.0. A concentrate with WO3 grade of 52.0% and recovery of 78.4% was achieved by the run-of-mine ore batch flotation test. In addition, the mechanism of the selective separation was investigated by zeta-potential measurements, FTIR spectra and XPS analyses, which demonstrated that SNaOL absorbed more strongly and selectively on the “scheelite + SGM” surface than on the “talc + SGM” surface, while SGM could more selectively interact on the talc surface than on the scheelite surface. SGM absorbed on the talc surface by chemical adsorption between the Mg/Si atom of the talc surface and OH group in SGM molecule. Keywords: Scheelite, Talc, Sesbania gum, Sulfonated oleic acid, Adsorption mechanism |
url |
http://www.sciencedirect.com/science/article/pii/S2238785417304933 |
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