trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)

trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)

The well known title compound, trans-[Mo(C18H15P)2(CO)4], has not been studied previously by X-ray crystallography, unlike its cis isomer. The complex possesses crystallographically imposed inversion symmetry, with the Mo atom residing on an inversion centre (1a Wyckoff position). The two triphenylp...

Full description

Bibliographic Details
Main Authors: Greyson W. Waldhart, Neal P. Mankad
Format: Article
Language:English
Published: International Union of Crystallography 2014-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814000300
id doaj-149b52c96d894e5bb0dc0dfaea0fc39e
record_format Article
spelling doaj-149b52c96d894e5bb0dc0dfaea0fc39e2020-11-25T01:05:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-02-01702m36m3610.1107/S1600536814000300pj2007trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)Greyson W. Waldhart0Neal P. Mankad1Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, IL 60607, USADepartment of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, IL 60607, USAThe well known title compound, trans-[Mo(C18H15P)2(CO)4], has not been studied previously by X-ray crystallography, unlike its cis isomer. The complex possesses crystallographically imposed inversion symmetry, with the Mo atom residing on an inversion centre (1a Wyckoff position). The two triphenylphosphane groups are arranged in a staggered orientation. Each of the phenyl groups exhibits significantly different Mo—P—C—C torsion angles ranging from 2.6 (2) to 179.4 (1)°, most likely due to steric interactions based upon their positions relative to the carbonyl ligands. http://scripts.iucr.org/cgi-bin/paper?S1600536814000300
collection DOAJ
language English
format Article
sources DOAJ
author Greyson W. Waldhart
Neal P. Mankad
spellingShingle Greyson W. Waldhart
Neal P. Mankad
trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)
Acta Crystallographica Section E
author_facet Greyson W. Waldhart
Neal P. Mankad
author_sort Greyson W. Waldhart
title trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)
title_short trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)
title_full trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)
title_fullStr trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)
title_full_unstemmed trans-Tetracarbonylbis(triphenylphosphane-κP)molybdenum(0)
title_sort trans-tetracarbonylbis(triphenylphosphane-κp)molybdenum(0)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-02-01
description The well known title compound, trans-[Mo(C18H15P)2(CO)4], has not been studied previously by X-ray crystallography, unlike its cis isomer. The complex possesses crystallographically imposed inversion symmetry, with the Mo atom residing on an inversion centre (1a Wyckoff position). The two triphenylphosphane groups are arranged in a staggered orientation. Each of the phenyl groups exhibits significantly different Mo—P—C—C torsion angles ranging from 2.6 (2) to 179.4 (1)°, most likely due to steric interactions based upon their positions relative to the carbonyl ligands.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814000300
work_keys_str_mv AT greysonwwaldhart transtetracarbonylbistriphenylphosphanekpmolybdenum0
AT nealpmankad transtetracarbonylbistriphenylphosphanekpmolybdenum0
_version_ 1725195094119677952

Similar Items