Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate

Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate

The structure of the dinuclear title complex, [Cu2(C10H8N7)2(NO3)2(H2O)2]·2H2O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The CuII ions in the dimer display a distorted octahedral coordination geometry and are bridged by two triazole rings, forming an...

Full description

Bibliographic Details
Main Author: Roman Doroschuk
Format: Article
Language:English
Published: International Union of Crystallography 2016-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
1,2,4-triazole
dinuclear copper complex
hydrogen bonds
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016003479
id doaj-1355976d64aa45848ccc810bbff5e563
record_format Article
spelling doaj-1355976d64aa45848ccc810bbff5e5632020-11-24T21:54:44ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-04-0172448648810.1107/S2056989016003479rz5185Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrateRoman Doroschuk0Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, 64, Volodymyrska Str., 01033, Kyiv, UkraineThe structure of the dinuclear title complex, [Cu2(C10H8N7)2(NO3)2(H2O)2]·2H2O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The CuII ions in the dimer display a distorted octahedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu2N4 core (r.m.s. deviation = 0.049 Å). In the crystal, O—H...O, O—H...N and C—H...O hydrogen bonds and π–π interactions link the molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989016003479crystal structure1,2,4-triazoledinuclear copper complexhydrogen bonds
collection DOAJ
language English
format Article
sources DOAJ
author Roman Doroschuk
spellingShingle Roman Doroschuk
Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
1,2,4-triazole
dinuclear copper complex
hydrogen bonds
author_facet Roman Doroschuk
author_sort Roman Doroschuk
title Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate
title_short Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate
title_full Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate
title_fullStr Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate
title_full_unstemmed Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate
title_sort crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(ii)] dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2016-04-01
description The structure of the dinuclear title complex, [Cu2(C10H8N7)2(NO3)2(H2O)2]·2H2O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The CuII ions in the dimer display a distorted octahedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu2N4 core (r.m.s. deviation = 0.049 Å). In the crystal, O—H...O, O—H...N and C—H...O hydrogen bonds and π–π interactions link the molecules into a three-dimensional network.
topic crystal structure
1,2,4-triazole
dinuclear copper complex
hydrogen bonds
url http://scripts.iucr.org/cgi-bin/paper?S2056989016003479
work_keys_str_mv AT romandoroschuk crystalstructureofbism23pyridin2yl5124triazol1ylmethyl124triazolatobisaquanitratocopperiidihydrate
_version_ 1725866082371108864

Similar Items