Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate

Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate

In the title organic–inorganic hybrid compound, (C4H10NO)3[H6CrMo6O24]·4H2O, the Anderson-type [H6CrMo6O24]3− polyoxoanion is centrosymmetric, with the CrIII ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations...

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Main Authors: Yan-Yan Yang, Yu Song, Li-Ye Liu, Xiao-Shu Qu
Format: Article
Language:English
Published: International Union of Crystallography 2011-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811018149
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spelling doaj-132e4d8a0ddb4900b0593027aa9de61f2020-11-25T01:34:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m776m77610.1107/S1600536811018149Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrateYan-Yan YangYu SongLi-Ye LiuXiao-Shu QuIn the title organic–inorganic hybrid compound, (C4H10NO)3[H6CrMo6O24]·4H2O, the Anderson-type [H6CrMo6O24]3− polyoxoanion is centrosymmetric, with the CrIII ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Intermolecular N—H...O and O—H...O hydrogen bonds link the cations, polyoxoanions and uncoordinated water molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536811018149
collection DOAJ
language English
format Article
sources DOAJ
author Yan-Yan Yang
Yu Song
Li-Ye Liu
Xiao-Shu Qu
spellingShingle Yan-Yan Yang
Yu Song
Li-Ye Liu
Xiao-Shu Qu
Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate
Acta Crystallographica Section E
author_facet Yan-Yan Yang
Yu Song
Li-Ye Liu
Xiao-Shu Qu
author_sort Yan-Yan Yang
title Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate
title_short Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate
title_full Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate
title_fullStr Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate
title_full_unstemmed Tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(VI)chromate(III) tetrahydrate
title_sort tris(morpholinium) hexa-μ3-hydroxido-hexa-μ2-oxido-dodecaoxidohexamolybdenum(vi)chromate(iii) tetrahydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-06-01
description In the title organic–inorganic hybrid compound, (C4H10NO)3[H6CrMo6O24]·4H2O, the Anderson-type [H6CrMo6O24]3− polyoxoanion is centrosymmetric, with the CrIII ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Intermolecular N—H...O and O—H...O hydrogen bonds link the cations, polyoxoanions and uncoordinated water molecules.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811018149
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AT yusong trismorpholiniumhexaamp9563hydroxidohexaamp9562oxidododecaoxidohexamolybdenumvichromateiiitetrahydrate
AT liyeliu trismorpholiniumhexaamp9563hydroxidohexaamp9562oxidododecaoxidohexamolybdenumvichromateiiitetrahydrate
AT xiaoshuqu trismorpholiniumhexaamp9563hydroxidohexaamp9562oxidododecaoxidohexamolybdenumvichromateiiitetrahydrate
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