Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: Ghassoul

The aim of this study is based on natural clay as an adsorbent in the elimination of polyphenols from olive mill wastewater (OMW). This clay was analyzed using XRD, SEM/EDX, FTIR, surface area measurement (BET method), thermal analysis (TGA/DTA), and X-ray fluorescence (XRF) and then used in adsorpt...

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Main Authors: Safae Allaoui, Mohammed Naciri Bennani, Hamid Ziyat, Omar Qabaqous, Najib Tijani, Najim Ittobane
Format: Article
Language:English
Published: Hindawi Limited 2020-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2020/7293189
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spelling doaj-1329f266fdb642958e0bd7e4cde4a34c2020-11-25T02:11:11ZengHindawi LimitedJournal of Chemistry2090-90632090-90712020-01-01202010.1155/2020/72931897293189Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: GhassoulSafae Allaoui0Mohammed Naciri Bennani1Hamid Ziyat2Omar Qabaqous3Najib Tijani4Najim Ittobane5Laboratory of Chemistry-Biology Applied to the Environment, Research Team “Applied Materials and Catalysis”, Chemistry Department, Faculty of Sciences, Moulay-Ismaïl University, BP. 11201-Zitoune, Meknes 50000, MoroccoLaboratory of Chemistry-Biology Applied to the Environment, Research Team “Applied Materials and Catalysis”, Chemistry Department, Faculty of Sciences, Moulay-Ismaïl University, BP. 11201-Zitoune, Meknes 50000, MoroccoLaboratory of Chemistry-Biology Applied to the Environment, Research Team “Applied Materials and Catalysis”, Chemistry Department, Faculty of Sciences, Moulay-Ismaïl University, BP. 11201-Zitoune, Meknes 50000, MoroccoLaboratory of Chemistry-Biology Applied to the Environment, Research Team “Applied Materials and Catalysis”, Chemistry Department, Faculty of Sciences, Moulay-Ismaïl University, BP. 11201-Zitoune, Meknes 50000, MoroccoResearch Team “Membrane Materials and Separation Processes, Chemistry Department, Faculty of Science, Moulay-Ismaïl University, BP. 11201-Zitoune, Meknes 50000, MoroccoResearch Team “Biomolecular and Macromolecular Chemistry, Chemistry Department, Faculty of Science, Moulay-Ismaíl University, BP. 11201-Zitoune, Meknes 50000, MoroccoThe aim of this study is based on natural clay as an adsorbent in the elimination of polyphenols from olive mill wastewater (OMW). This clay was analyzed using XRD, SEM/EDX, FTIR, surface area measurement (BET method), thermal analysis (TGA/DTA), and X-ray fluorescence (XRF) and then used in adsorption experiments. The results reveal that the best quantity of adsorption of polyphenols is 161 mg/g at the temperature of 25°C, but they decrease at 35°C and 45°C. A great agreement with pseudo-second-order and Freundlich model is represented by kinetic and isotherms models, and several parameters such as ΔG0, ΔS0, and ΔH0 were determined using the thermodynamic function relationship.http://dx.doi.org/10.1155/2020/7293189
collection DOAJ
language English
format Article
sources DOAJ
author Safae Allaoui
Mohammed Naciri Bennani
Hamid Ziyat
Omar Qabaqous
Najib Tijani
Najim Ittobane
spellingShingle Safae Allaoui
Mohammed Naciri Bennani
Hamid Ziyat
Omar Qabaqous
Najib Tijani
Najim Ittobane
Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: Ghassoul
Journal of Chemistry
author_facet Safae Allaoui
Mohammed Naciri Bennani
Hamid Ziyat
Omar Qabaqous
Najib Tijani
Najim Ittobane
author_sort Safae Allaoui
title Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: Ghassoul
title_short Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: Ghassoul
title_full Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: Ghassoul
title_fullStr Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: Ghassoul
title_full_unstemmed Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: Ghassoul
title_sort kinetic study of the adsorption of polyphenols from olive mill wastewater onto natural clay: ghassoul
publisher Hindawi Limited
series Journal of Chemistry
issn 2090-9063
2090-9071
publishDate 2020-01-01
description The aim of this study is based on natural clay as an adsorbent in the elimination of polyphenols from olive mill wastewater (OMW). This clay was analyzed using XRD, SEM/EDX, FTIR, surface area measurement (BET method), thermal analysis (TGA/DTA), and X-ray fluorescence (XRF) and then used in adsorption experiments. The results reveal that the best quantity of adsorption of polyphenols is 161 mg/g at the temperature of 25°C, but they decrease at 35°C and 45°C. A great agreement with pseudo-second-order and Freundlich model is represented by kinetic and isotherms models, and several parameters such as ΔG0, ΔS0, and ΔH0 were determined using the thermodynamic function relationship.
url http://dx.doi.org/10.1155/2020/7293189
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AT hamidziyat kineticstudyoftheadsorptionofpolyphenolsfromolivemillwastewaterontonaturalclayghassoul
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