2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate

2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate

In the title compound, (C14H13N2)[FeCl4]·CH3OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl4− anion and methanol solvent molecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the FeIII at...

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Main Authors: Ehsan Bahojb Noruzi, Nasser Safari, Vahid Amani, Behrouz Notash
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812025111
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spelling doaj-11dd0e9b8e9e4db19f954307c9716bcd2020-11-25T02:16:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m905m90510.1107/S16005368120251112,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvateEhsan Bahojb NoruziNasser SafariVahid AmaniBehrouz NotashIn the title compound, (C14H13N2)[FeCl4]·CH3OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl4− anion and methanol solvent molecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the FeIII atom has a tetrahedral geometry. H atoms of the methanol molecule are disordered over two sets of sites around the twofold axis. In the crystal, π–π contacts between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.6535 (16) and 3.5522 (17) Å] and intermolecular O—H...N and N—H...O hydrogen bonds stabilize the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812025111
collection DOAJ
language English
format Article
sources DOAJ
author Ehsan Bahojb Noruzi
Nasser Safari
Vahid Amani
Behrouz Notash
spellingShingle Ehsan Bahojb Noruzi
Nasser Safari
Vahid Amani
Behrouz Notash
2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate
Acta Crystallographica Section E
author_facet Ehsan Bahojb Noruzi
Nasser Safari
Vahid Amani
Behrouz Notash
author_sort Ehsan Bahojb Noruzi
title 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate
title_short 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate
title_full 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate
title_fullStr 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate
title_full_unstemmed 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate
title_sort 2,9-dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(iii) methanol monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-07-01
description In the title compound, (C14H13N2)[FeCl4]·CH3OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl4− anion and methanol solvent molecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the FeIII atom has a tetrahedral geometry. H atoms of the methanol molecule are disordered over two sets of sites around the twofold axis. In the crystal, π–π contacts between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.6535 (16) and 3.5522 (17) Å] and intermolecular O—H...N and N—H...O hydrogen bonds stabilize the structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812025111
work_keys_str_mv AT ehsanbahojbnoruzi 29dimethyl110phenanthrolin1iumtetrachloridoferrateiiimethanolmonosolvate
AT nassersafari 29dimethyl110phenanthrolin1iumtetrachloridoferrateiiimethanolmonosolvate
AT vahidamani 29dimethyl110phenanthrolin1iumtetrachloridoferrateiiimethanolmonosolvate
AT behrouznotash 29dimethyl110phenanthrolin1iumtetrachloridoferrateiiimethanolmonosolvate
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