(6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate

(6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate

The title compound, [Cu(C11H12N4O3)(C18H15P)2]PF6, is the third example reported in the literature of a five-coordinated CuIP2NO2 system. The metal is coordinated to both PPh3 molecules through the P atoms and to the pyrazine ring of the lumazine molecule through an N atom in a trigonal&#821...

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Main Authors: Francisco Hueso-Ureña, Nuria A. Illán-Cabeza, Sonia B. Jiménez-Pulido, Miguel N. Moreno-Carretero
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810000735
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spelling doaj-113b53bb82e24dbeab05e2bd6fd00b272020-11-25T00:50:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m145m14610.1107/S1600536810000735(6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphateFrancisco Hueso-UreñaNuria A. Illán-CabezaSonia B. Jiménez-PulidoMiguel N. Moreno-CarreteroThe title compound, [Cu(C11H12N4O3)(C18H15P)2]PF6, is the third example reported in the literature of a five-coordinated CuIP2NO2 system. The metal is coordinated to both PPh3 molecules through the P atoms and to the pyrazine ring of the lumazine molecule through an N atom in a trigonal–planar arrangement; two additional coordinated O atoms, at Cu—O distances longer than 2.46 Å, complete the coordination. The coordination environment can be described as an intermediate square-pyramidal/trigonal–bipyramidal (SP/TBP) polyhedron. http://scripts.iucr.org/cgi-bin/paper?S1600536810000735
collection DOAJ
language English
format Article
sources DOAJ
author Francisco Hueso-Ureña
Nuria A. Illán-Cabeza
Sonia B. Jiménez-Pulido
Miguel N. Moreno-Carretero
spellingShingle Francisco Hueso-Ureña
Nuria A. Illán-Cabeza
Sonia B. Jiménez-Pulido
Miguel N. Moreno-Carretero
(6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate
Acta Crystallographica Section E
author_facet Francisco Hueso-Ureña
Nuria A. Illán-Cabeza
Sonia B. Jiménez-Pulido
Miguel N. Moreno-Carretero
author_sort Francisco Hueso-Ureña
title (6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate
title_short (6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate
title_full (6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate
title_fullStr (6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate
title_full_unstemmed (6-Acetyl-1,3,7-trimethyllumazine-κ3O4,N5,O6)bis(triphenylphosphine-κP)copper(I) hexafluoridophosphate
title_sort (6-acetyl-1,3,7-trimethyllumazine-κ3o4,n5,o6)bis(triphenylphosphine-κp)copper(i) hexafluoridophosphate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-02-01
description The title compound, [Cu(C11H12N4O3)(C18H15P)2]PF6, is the third example reported in the literature of a five-coordinated CuIP2NO2 system. The metal is coordinated to both PPh3 molecules through the P atoms and to the pyrazine ring of the lumazine molecule through an N atom in a trigonal–planar arrangement; two additional coordinated O atoms, at Cu—O distances longer than 2.46 Å, complete the coordination. The coordination environment can be described as an intermediate square-pyramidal/trigonal–bipyramidal (SP/TBP) polyhedron.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810000735
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AT nuriaaillamp225ncabeza 6acetyl137trimethyllumazineamp9543o4n5o6bistriphenylphosphineamp954pcopperihexafluoridophosphate
AT soniabjimamp233nezpulido 6acetyl137trimethyllumazineamp9543o4n5o6bistriphenylphosphineamp954pcopperihexafluoridophosphate
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