Preparation and Cycling Performance of Iron or Iron Oxide Containing Amorphous Al-Li Alloys as Electrodes
Crystalline phase transitions cause volume changes, which entails a fast destroying of the electrode. Non-crystalline states may avoid this circumstance. Herein we present structural and electrochemical investigations of pre-lithiated, amorphous Al39Li43Fe13Si5-powders, to be used as electrode mater...
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MDPI AG
2014-12-01
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| Series: | Inorganics |
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| Online Access: | http://www.mdpi.com/2304-6740/2/4/674 |
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doaj-110b0a92824949b5b51b1fb5bb394d142020-11-24T23:12:56ZengMDPI AGInorganics2304-67402014-12-012467468210.3390/inorganics2040674inorganics2040674Preparation and Cycling Performance of Iron or Iron Oxide Containing Amorphous Al-Li Alloys as ElectrodesFranziska Thoss0Lars Giebeler1Karsten Weißer2Jörg Feller3Jürgen Eckert4Leibniz Institute for Solid State and Materials Research Dresden (IFW), Institute for Complex Materials, Helmholtzstr. 20, D-01069 Dresden, GermanyLeibniz Institute for Solid State and Materials Research Dresden (IFW), Institute for Complex Materials, Helmholtzstr. 20, D-01069 Dresden, GermanyLeibniz Institute for Solid State and Materials Research Dresden (IFW), Institute for Complex Materials, Helmholtzstr. 20, D-01069 Dresden, GermanyHochschule für Technik und Wirtschaft Dresden, Faculty of Mechanical Engineering/Process Engineering, Friedrich-List-Platz 1, D-01069 Dresden, GermanyLeibniz Institute for Solid State and Materials Research Dresden (IFW), Institute for Complex Materials, Helmholtzstr. 20, D-01069 Dresden, GermanyCrystalline phase transitions cause volume changes, which entails a fast destroying of the electrode. Non-crystalline states may avoid this circumstance. Herein we present structural and electrochemical investigations of pre-lithiated, amorphous Al39Li43Fe13Si5-powders, to be used as electrode material for Li-ion batteries. Powders of master alloys with the compositions Al39Li43Fe13Si5 and Al39Li43Fe13Si5 + 5 mass-% FeO were prepared via ball milling and achieved amorphous/nanocrystalline states after 56 and 21.6 h, respectively. In contrast to their Li-free amorphous pendant Al78Fe13Si9, both powders showed specific capacities of about 400 and 700 Ah/kgAl, respectively, after the third cycle.http://www.mdpi.com/2304-6740/2/4/674Li-ion batteriesmetallic anodesamorphousball millingiron oxide |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Franziska Thoss Lars Giebeler Karsten Weißer Jörg Feller Jürgen Eckert |
| spellingShingle |
Franziska Thoss Lars Giebeler Karsten Weißer Jörg Feller Jürgen Eckert Preparation and Cycling Performance of Iron or Iron Oxide Containing Amorphous Al-Li Alloys as Electrodes Inorganics Li-ion batteries metallic anodes amorphous ball milling iron oxide |
| author_facet |
Franziska Thoss Lars Giebeler Karsten Weißer Jörg Feller Jürgen Eckert |
| author_sort |
Franziska Thoss |
| title |
Preparation and Cycling Performance of Iron or Iron Oxide Containing Amorphous Al-Li Alloys as Electrodes |
| title_short |
Preparation and Cycling Performance of Iron or Iron Oxide Containing Amorphous Al-Li Alloys as Electrodes |
| title_full |
Preparation and Cycling Performance of Iron or Iron Oxide Containing Amorphous Al-Li Alloys as Electrodes |
| title_fullStr |
Preparation and Cycling Performance of Iron or Iron Oxide Containing Amorphous Al-Li Alloys as Electrodes |
| title_full_unstemmed |
Preparation and Cycling Performance of Iron or Iron Oxide Containing Amorphous Al-Li Alloys as Electrodes |
| title_sort |
preparation and cycling performance of iron or iron oxide containing amorphous al-li alloys as electrodes |
| publisher |
MDPI AG |
| series |
Inorganics |
| issn |
2304-6740 |
| publishDate |
2014-12-01 |
| description |
Crystalline phase transitions cause volume changes, which entails a fast destroying of the electrode. Non-crystalline states may avoid this circumstance. Herein we present structural and electrochemical investigations of pre-lithiated, amorphous Al39Li43Fe13Si5-powders, to be used as electrode material for Li-ion batteries. Powders of master alloys with the compositions Al39Li43Fe13Si5 and Al39Li43Fe13Si5 + 5 mass-% FeO were prepared via ball milling and achieved amorphous/nanocrystalline states after 56 and 21.6 h, respectively. In contrast to their Li-free amorphous pendant Al78Fe13Si9, both powders showed specific capacities of about 400 and 700 Ah/kgAl, respectively, after the third cycle. |
| topic |
Li-ion batteries metallic anodes amorphous ball milling iron oxide |
| url |
http://www.mdpi.com/2304-6740/2/4/674 |
| work_keys_str_mv |
AT franziskathoss preparationandcyclingperformanceofironorironoxidecontainingamorphousallialloysaselectrodes AT larsgiebeler preparationandcyclingperformanceofironorironoxidecontainingamorphousallialloysaselectrodes AT karstenweißer preparationandcyclingperformanceofironorironoxidecontainingamorphousallialloysaselectrodes AT jorgfeller preparationandcyclingperformanceofironorironoxidecontainingamorphousallialloysaselectrodes AT jurgeneckert preparationandcyclingperformanceofironorironoxidecontainingamorphousallialloysaselectrodes |
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