Crystal structures of two CuII compounds: catena-poly[[chloridocopper(II)]-μ-N-[ethoxy(pyridin-2-yl)methylidene]-N′-[oxido(pyridin-3-yl)methylidene]hydrazine-κ4N,N′,O:N′′] and di-μ-chlorido-1:4κ2Cl:Cl-2:3κ2Cl:Cl-dichlorido-2κCl,4κCl-bis[μ3-ethoxy(pyridin-2-yl)methanolato-1:2:3κ3O:N,O:O;1:3:4κ3O:O:N,O]bis[μ2-ethoxy(pyridin-2-yl)methanolato-1:2κ3N,O:O;3:4κ3N,O:O]tetracopper(II)

Crystal structures of two CuII compounds: catena-poly[[chloridocopper(II)]-μ-N-[ethoxy(pyridin-2-yl)methylidene]-N′-[oxido(pyridin-3-yl)methylidene]hydrazine-κ4N,N′,O:N′′] and di-μ-chlorido-1:4κ2Cl:Cl-2:3κ2Cl:Cl-dichlorido-2κCl,4κCl-bis[μ3-ethoxy(pyridin-2-yl)methanolato-1:2:3κ3O:N,O:O;1:3:4κ3O:O:N,O]bis[μ2-ethoxy(pyridin-2-yl)methanolato-1:2κ3N,O:O;3:4κ3N,O:O]tetracopper(II)

Two CuII complexes [Cu(C14H13N4O2)Cl]n, I, and [Cu4(C8H10NO2)4Cl4]n, II, have been synthesized. In the structure of the mononuclear complex I, each ligand is coordinated to two metal centers. The basal plane around the CuII cation is formed by one chloride anion, one oxygen atom, one imino and one p...

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Bibliographic Details
Main Authors: Ousmane Sall, Farba Bouyagui Tamboura, Adama Sy, Aliou Hamady Barry, Elhadj Ibrahima Thiam, Mohamed Gaye, Javier Ellena
Format: Article
Language:English
Published: International Union of Crystallography 2019-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
copper complex
coordination polymer
open-cube structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019008922

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