(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate

(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate

In the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen...

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Bibliographic Details
Main Authors: Guang-Chuan Ou, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810042637
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spelling doaj-10c5eb6ab3f2431a89bcc91089fadcbd2020-11-24T22:15:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1468m146810.1107/S1600536810042637(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvateGuang-Chuan OuSeik Weng NgIn the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen bonds into centrosymmetric dimers. Further N—H...O and O—H...O hydrogen bonds link the complex molecules and the perchlorate ions. http://scripts.iucr.org/cgi-bin/paper?S1600536810042637
collection DOAJ
language English
format Article
sources DOAJ
author Guang-Chuan Ou
Seik Weng Ng
spellingShingle Guang-Chuan Ou
Seik Weng Ng
(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
Acta Crystallographica Section E
author_facet Guang-Chuan Ou
Seik Weng Ng
author_sort Guang-Chuan Ou
title (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_short (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_full (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_fullStr (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_full_unstemmed (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_sort (2-carboxyacetato-κ2o1,o1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4n,n′,n′′,n′′′)nickel(ii) perchlorate acetonitrile solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-11-01
description In the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen bonds into centrosymmetric dimers. Further N—H...O and O—H...O hydrogen bonds link the complex molecules and the perchlorate ions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810042637
work_keys_str_mv AT guangchuanou 2carboxyacetatoamp9542o1o1amp8242rac557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchlorateacetonitrilesolvate
AT seikwengng 2carboxyacetatoamp9542o1o1amp8242rac557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchlorateacetonitrilesolvate
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