Ultrasonic Treatment Enhanced Surface Modification of Titanium Oxide by Tailor-Made Surface-Active Polymers

The surface modification of titanium dioxide in aqueous dispersions of specially tailor-made periodic acrylic acid/isobutylene copolymers, poly(acrylic acid)/polystyrene graft copolymers, and hydrophobically modified polyethyleneoxide urethane (HEUR) by ultrasonic treatment was studied. The pigment...

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Bibliographic Details
Main Authors: N. Bulychev, E. Kisterev, H. Reimann, C. Schaller, C. D. Eisenbach
Format: Article
Language:English
Published: al-Farabi Kazakh National University 2009-04-01
Series:Eurasian Chemico-Technological Journal 
Online Access:http://ect-journal.kz/index.php/ectj/article/view/520
Description
Summary:The surface modification of titanium dioxide in aqueous dispersions of specially tailor-made periodic acrylic acid/isobutylene copolymers, poly(acrylic acid)/polystyrene graft copolymers, and hydrophobically modified polyethyleneoxide urethane (HEUR) by ultrasonic treatment was studied. The pigment surface modification by the above copolymers was comparatively investigated regarding conventional adsorption as contrasted to an ultrasonic treatment assisted procedure. The course and efficiency of the polymer adsorpption onto the pigment surface was quantified by electrokinetic sonic amplitude measurements. The higher efficiency of the pigment surface coating by the copolymers as achieved by ultrasonic treatment varies with the copolymer architecture and is a consequence of ultrasonically induced pigment surface activation.
ISSN:1562-3920
2522-4867