Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrate

Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrate

The MnII ion in the title compound, [Mn(CH3CO2)2(C15H11N3)]·2H2O, is seven-coordinated in a considerably distorted pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and...

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Main Author: Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811055802
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spelling doaj-10a51153d5e747e2a173f6b271dae1462020-11-24T21:28:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m124m12410.1107/S1600536811055802Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrateKwang HaThe MnII ion in the title compound, [Mn(CH3CO2)2(C15H11N3)]·2H2O, is seven-coordinated in a considerably distorted pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, making dihedral angles of 13.6 (2) and 5.7 (2)°. The complex and solvent water molecules are linked by intermolecular O—H...O hydrogen bonds into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811055802
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
spellingShingle Kwang Ha
Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrate
Acta Crystallographica Section E
author_facet Kwang Ha
author_sort Kwang Ha
title Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrate
title_short Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrate
title_full Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrate
title_fullStr Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrate
title_full_unstemmed Bis(acetato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)manganese(II) dihydrate
title_sort bis(acetato-κ2o,o′)(2,2′:6′,2′′-terpyridine-κ3n,n′,n′′)manganese(ii) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description The MnII ion in the title compound, [Mn(CH3CO2)2(C15H11N3)]·2H2O, is seven-coordinated in a considerably distorted pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, making dihedral angles of 13.6 (2) and 5.7 (2)°. The complex and solvent water molecules are linked by intermolecular O—H...O hydrogen bonds into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811055802
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