Physico-Chemical Study of Some Cross Conjugated Systems, Part II
Abstract<br /> A series of cross-conjugated enones [1-10] are condensed with menthone under (PTC) technique. The structures of the new products [11-20] were identified by spectral analysis. The probable reaction mechanism for each condensation is investigated by theoretical approach using both...
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College of Education for Pure Sciences
1999-11-01
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doaj-10629be78b3146079ed2cddc958c739c2020-11-25T01:37:09ZaraCollege of Education for Pure Sciencesمجلة التربية والعلم1812-125X2664-25301999-11-0124311310.33899/edusj.1999.5880258802Physico-Chemical Study of Some Cross Conjugated Systems, Part IIM. Shandala0M. Al-Shamamry1H. Al-Wahab2R. Salih3Department of Chemistry, College of Science, University of Mosul, Mosul, IraqDepartment of Chemistry, College of Science, University of Mosul, Mosul, IraqDepartment of Chemistry, College of Science, University of Mosul, Mosul, IraqDepartment of Chemistry, College of Education, University of Mosul, Mosul, IraqAbstract<br /> A series of cross-conjugated enones [1-10] are condensed with menthone under (PTC) technique. The structures of the new products [11-20] were identified by spectral analysis. The probable reaction mechanism for each condensation is investigated by theoretical approach using both quantum mechanic (AM1) and molecular (MM2) computational methods. The unique behavior of these cross conjugated enones toward nucleophilic addition orientation, substituent effect on the electronic distribution, and the polarity of the molecules have been examined.https://edusj.mosuljournals.com/article_58802_c7dd416244021807ab3880d29d4aad2e.pdfphysico-chemical studyو cross conjugated systemsptc technique |
collection |
DOAJ |
language |
Arabic |
format |
Article |
sources |
DOAJ |
author |
M. Shandala M. Al-Shamamry H. Al-Wahab R. Salih |
spellingShingle |
M. Shandala M. Al-Shamamry H. Al-Wahab R. Salih Physico-Chemical Study of Some Cross Conjugated Systems, Part II مجلة التربية والعلم physico-chemical studyو cross conjugated systems ptc technique |
author_facet |
M. Shandala M. Al-Shamamry H. Al-Wahab R. Salih |
author_sort |
M. Shandala |
title |
Physico-Chemical Study of Some Cross Conjugated Systems, Part II |
title_short |
Physico-Chemical Study of Some Cross Conjugated Systems, Part II |
title_full |
Physico-Chemical Study of Some Cross Conjugated Systems, Part II |
title_fullStr |
Physico-Chemical Study of Some Cross Conjugated Systems, Part II |
title_full_unstemmed |
Physico-Chemical Study of Some Cross Conjugated Systems, Part II |
title_sort |
physico-chemical study of some cross conjugated systems, part ii |
publisher |
College of Education for Pure Sciences |
series |
مجلة التربية والعلم |
issn |
1812-125X 2664-2530 |
publishDate |
1999-11-01 |
description |
Abstract<br /> A series of cross-conjugated enones [1-10] are condensed with menthone under (PTC) technique. The structures of the new products [11-20] were identified by spectral analysis. The probable reaction mechanism for each condensation is investigated by theoretical approach using both quantum mechanic (AM1) and molecular (MM2) computational methods. The unique behavior of these cross conjugated enones toward nucleophilic addition orientation, substituent effect on the electronic distribution, and the polarity of the molecules have been examined. |
topic |
physico-chemical studyو cross conjugated systems ptc technique |
url |
https://edusj.mosuljournals.com/article_58802_c7dd416244021807ab3880d29d4aad2e.pdf |
work_keys_str_mv |
AT mshandala physicochemicalstudyofsomecrossconjugatedsystemspartii AT malshamamry physicochemicalstudyofsomecrossconjugatedsystemspartii AT halwahab physicochemicalstudyofsomecrossconjugatedsystemspartii AT rsalih physicochemicalstudyofsomecrossconjugatedsystemspartii |
_version_ |
1725059398357745664 |