Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate

Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate

In the title complex, [Fe(C12H8N3O2)2]ClO4·CH3OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridylcarbonyl)pyridine-2-carboximidate (bpca) ligands and exhibits a distorted octahedral coordination by six bpca N atoms. A classical O—H...O hydrogen bond exists b...

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Main Author: Dayu Wu
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809040549
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spelling doaj-1046ead92d954dc19e77de438b3262a22020-11-25T01:17:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1340m134010.1107/S1600536809040549Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvateDayu WuIn the title complex, [Fe(C12H8N3O2)2]ClO4·CH3OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridylcarbonyl)pyridine-2-carboximidate (bpca) ligands and exhibits a distorted octahedral coordination by six bpca N atoms. A classical O—H...O hydrogen bond exists between the methanol solvent molecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5–400 K. http://scripts.iucr.org/cgi-bin/paper?S1600536809040549
collection DOAJ
language English
format Article
sources DOAJ
author Dayu Wu
spellingShingle Dayu Wu
Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
Acta Crystallographica Section E
author_facet Dayu Wu
author_sort Dayu Wu
title Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_short Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_full Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_fullStr Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_full_unstemmed Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_sort bis[n-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(iii) perchlorate methanol solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description In the title complex, [Fe(C12H8N3O2)2]ClO4·CH3OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridylcarbonyl)pyridine-2-carboximidate (bpca) ligands and exhibits a distorted octahedral coordination by six bpca N atoms. A classical O—H...O hydrogen bond exists between the methanol solvent molecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5–400 K.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809040549
work_keys_str_mv AT dayuwu bisn2pyridylcarbonylpyridine2carboximidatoironiiiperchloratemethanolsolvate
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