Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
In the title complex, [Fe(C12H8N3O2)2]ClO4·CH3OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridylcarbonyl)pyridine-2-carboximidate (bpca) ligands and exhibits a distorted octahedral coordination by six bpca N atoms. A classical O—H...O hydrogen bond exists b...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-11-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809040549 |
| Summary: | In the title complex, [Fe(C12H8N3O2)2]ClO4·CH3OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridylcarbonyl)pyridine-2-carboximidate (bpca) ligands and exhibits a distorted octahedral coordination by six bpca N atoms. A classical O—H...O hydrogen bond exists between the methanol solvent molecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5–400 K. |
|---|---|
| ISSN: | 1600-5368 |