Cleaning of stone materials in the Cathedral de Valladolid (Spain)

Two types of black crusts showing gypsiferous and calcareous compositions are recognized on the front-walls of the Valladolid Cathedral. On the basis of several petrophysical parameters, in particular compacity, sorption and desorption kinematics of carbonate rocks used building the cathedral, we co...

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Bibliographic Details
Main Authors: R. Fort, M. C. López de Azcona, F. Mingarro
Format: Article
Language:English
Published: Consejo Superior de Investigaciones Científicas 2000-06-01
Series:Materiales de Construccion
Subjects:
Online Access:http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/408
Description
Summary:Two types of black crusts showing gypsiferous and calcareous compositions are recognized on the front-walls of the Valladolid Cathedral. On the basis of several petrophysical parameters, in particular compacity, sorption and desorption kinematics of carbonate rocks used building the cathedral, we conclude that the most appropriate cleaning method of the ashlars is washing with water. Highest efficiency of the method is attained with water at 90ºC and at a pressure of 120 bars. This assessment is valid for most of the carbonate rocks of the cathedral except for detrital pelmicrites because of their low compacity which makes that water pressure for cleaning must not exceed 50 bars. The processing of cleaning with water should be preceded by alkaline treatment (NaOH and EDTA) of the rock surface.
ISSN:0465-2746
1988-3226