2-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid
In the title compound, C16H14N2O4, the dihedral angle between the aromatic rings is 12.45 (6)°. The central C(=O)—N—N=C bridge is roughly planar (r.m.s. deviation = 0.0346 Å) and makes dihedral angles of 13.01&...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812028735 |
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doaj-0ede50f5dcce4994a2de4d461dba11fd2020-11-24T21:30:48ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687o2260o226110.1107/S16005368120287352-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acidHoong-Kun FunTze Shyang ChiaAhmed M. AlafeefyHatem A. Abdel-AzizIn the title compound, C16H14N2O4, the dihedral angle between the aromatic rings is 12.45 (6)°. The central C(=O)—N—N=C bridge is roughly planar (r.m.s. deviation = 0.0346 Å) and makes dihedral angles of 13.01 (7) and 0.56 (7)° with the attached phenyl and benzene rings, respectively. The acetic acid unit (r.m.s. deviation = 0.0066 Å) is twisted from its attached benzene ring [dihedral angle = 19.48 (6)°]. In the crystal, molecules are linked by O—H...(O,N), N—H...O and C—H...O hydrogen bonds into sheets lying parallel to the bc plane. A weak aromatic π–π stacking interaction is also observed [centroid–centroid distance = 3.7330 (7) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812028735 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Hoong-Kun Fun Tze Shyang Chia Ahmed M. Alafeefy Hatem A. Abdel-Aziz |
| spellingShingle |
Hoong-Kun Fun Tze Shyang Chia Ahmed M. Alafeefy Hatem A. Abdel-Aziz 2-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid Acta Crystallographica Section E |
| author_facet |
Hoong-Kun Fun Tze Shyang Chia Ahmed M. Alafeefy Hatem A. Abdel-Aziz |
| author_sort |
Hoong-Kun Fun |
| title |
2-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid |
| title_short |
2-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid |
| title_full |
2-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid |
| title_fullStr |
2-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid |
| title_full_unstemmed |
2-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid |
| title_sort |
2-{2-[(e)-(2-benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-07-01 |
| description |
In the title compound, C16H14N2O4, the dihedral angle between the aromatic rings is 12.45 (6)°. The central C(=O)—N—N=C bridge is roughly planar (r.m.s. deviation = 0.0346 Å) and makes dihedral angles of 13.01 (7) and 0.56 (7)° with the attached phenyl and benzene rings, respectively. The acetic acid unit (r.m.s. deviation = 0.0066 Å) is twisted from its attached benzene ring [dihedral angle = 19.48 (6)°]. In the crystal, molecules are linked by O—H...(O,N), N—H...O and C—H...O hydrogen bonds into sheets lying parallel to the bc plane. A weak aromatic π–π stacking interaction is also observed [centroid–centroid distance = 3.7330 (7) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812028735 |
| work_keys_str_mv |
AT hoongkunfun 22e2benzoylhydrazin1ylidenemethylphenoxyaceticacid AT tzeshyangchia 22e2benzoylhydrazin1ylidenemethylphenoxyaceticacid AT ahmedmalafeefy 22e2benzoylhydrazin1ylidenemethylphenoxyaceticacid AT hatemaabdelaziz 22e2benzoylhydrazin1ylidenemethylphenoxyaceticacid |
| _version_ |
1725961729455685632 |