Organocatalyzed synthesis of fluorinated poly(aryl thioethers)

Organocatalyzed synthesis of fluorinated poly(aryl thioethers)

Fluorinated poly(aryl thioethers), unlike their poly(aryl ethers) counterparts, have received little attention despite excellent physical properties displayed by many polysulfides. Here the authors show a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed nucleophilic...

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Main Authors: Nathaniel H. Park, Gabriel dos Passos Gomes, Mareva Fevre, Gavin O. Jones, Igor V. Alabugin, James L. Hedrick
Format: Article
Language:English
Published: Nature Publishing Group 2017-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-017-00186-3
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spelling doaj-0ecd61ec526244b7b2ab62ce50a86ce12021-01-31T12:33:57ZengNature Publishing GroupNature Communications2041-17232017-08-01811710.1038/s41467-017-00186-3Organocatalyzed synthesis of fluorinated poly(aryl thioethers)Nathaniel H. Park0Gabriel dos Passos Gomes1Mareva Fevre2Gavin O. Jones3Igor V. Alabugin4James L. Hedrick5IBM Almaden Research CenterDepartment of Chemistry and Biochemistry, Florida State UniversityIBM Almaden Research CenterIBM Almaden Research CenterDepartment of Chemistry and Biochemistry, Florida State UniversityIBM Almaden Research CenterFluorinated poly(aryl thioethers), unlike their poly(aryl ethers) counterparts, have received little attention despite excellent physical properties displayed by many polysulfides. Here the authors show a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed nucleophilic aromatic substitution of silyl-protected dithiols.https://doi.org/10.1038/s41467-017-00186-3
collection DOAJ
language English
format Article
sources DOAJ
author Nathaniel H. Park
Gabriel dos Passos Gomes
Mareva Fevre
Gavin O. Jones
Igor V. Alabugin
James L. Hedrick
spellingShingle Nathaniel H. Park
Gabriel dos Passos Gomes
Mareva Fevre
Gavin O. Jones
Igor V. Alabugin
James L. Hedrick
Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
Nature Communications
author_facet Nathaniel H. Park
Gabriel dos Passos Gomes
Mareva Fevre
Gavin O. Jones
Igor V. Alabugin
James L. Hedrick
author_sort Nathaniel H. Park
title Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_short Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_full Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_fullStr Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_full_unstemmed Organocatalyzed synthesis of fluorinated poly(aryl thioethers)
title_sort organocatalyzed synthesis of fluorinated poly(aryl thioethers)
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2017-08-01
description Fluorinated poly(aryl thioethers), unlike their poly(aryl ethers) counterparts, have received little attention despite excellent physical properties displayed by many polysulfides. Here the authors show a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed nucleophilic aromatic substitution of silyl-protected dithiols.
url https://doi.org/10.1038/s41467-017-00186-3
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AT gabrieldospassosgomes organocatalyzedsynthesisoffluorinatedpolyarylthioethers
AT marevafevre organocatalyzedsynthesisoffluorinatedpolyarylthioethers
AT gavinojones organocatalyzedsynthesisoffluorinatedpolyarylthioethers
AT igorvalabugin organocatalyzedsynthesisoffluorinatedpolyarylthioethers
AT jameslhedrick organocatalyzedsynthesisoffluorinatedpolyarylthioethers
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