Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate Salts

The metastable zone width (MZW) of lithium metaborate salts at various concentrations was determined using the laser technique. The solubility data for lithium metaborate salts was nearly the same in the presence of NaCl at various concentrations. The MZW of lithium metaborate salts decreased when t...

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Main Authors:	Dan Li, Yong Ma, Lingzong Meng, Yafei Guo, Tianlong Deng, Lan Yang
Format:	Article
Language:	English
Published:	MDPI AG 2019-03-01
Series:	Crystals
Subjects:	solubility metastable zone width lithium metaborate salts nucleation order
Online Access:	https://www.mdpi.com/2073-4352/9/4/182

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record_format	Article
spelling	doaj-0e5a44df7bc4452d880c9623821803462020-11-25T00:27:38ZengMDPI AGCrystals2073-43522019-03-019418210.3390/cryst9040182cryst9040182Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate SaltsDan Li0Yong Ma1Lingzong Meng2Yafei Guo3Tianlong Deng4Lan Yang5School of Chemistry and Chemical Engineering, Linyi University, Linyi 276000, ChinaSchool of Chemistry and Chemical Engineering, Linyi University, Linyi 276000, ChinaSchool of Chemistry and Chemical Engineering, Linyi University, Linyi 276000, ChinaTianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, ChinaTianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, ChinaSchool of Chemistry and Chemical Engineering, Linyi University, Linyi 276000, ChinaThe metastable zone width (MZW) of lithium metaborate salts at various concentrations was determined using the laser technique. The solubility data for lithium metaborate salts was nearly the same in the presence of NaCl at various concentrations. The MZW of lithium metaborate salts decreased when the stirring rate increased, but increased remarkably with increasing cooling rates and an increasing concentration of sodium chloride. The apparent secondary nucleation order for lithium metaborate salts was obtained using the Nývlt’s approach. The apparent secondary nucleation order <i>m</i> of lithium metaborate salts is 4.00 in a pure LiBO<sub>2</sub>−H<sub>2</sub>O system with an improved linear regression method. The <i>m</i> for lithium metaborate salts was enlarged in the system LiBO<sub>2</sub>−NaCl−H<sub>2</sub>O.https://www.mdpi.com/2073-4352/9/4/182solubilitymetastable zone widthlithium metaborate saltsnucleation order
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Dan Li Yong Ma Lingzong Meng Yafei Guo Tianlong Deng Lan Yang
spellingShingle	Dan Li Yong Ma Lingzong Meng Yafei Guo Tianlong Deng Lan Yang Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate Salts Crystals solubility metastable zone width lithium metaborate salts nucleation order
author_facet	Dan Li Yong Ma Lingzong Meng Yafei Guo Tianlong Deng Lan Yang
author_sort	Dan Li
title	Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate Salts
title_short	Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate Salts
title_full	Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate Salts
title_fullStr	Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate Salts
title_full_unstemmed	Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate Salts
title_sort	effect of impurity ions on solubility and metastable zone width of lithium metaborate salts
publisher	MDPI AG
series	Crystals
issn	2073-4352
publishDate	2019-03-01
description	The metastable zone width (MZW) of lithium metaborate salts at various concentrations was determined using the laser technique. The solubility data for lithium metaborate salts was nearly the same in the presence of NaCl at various concentrations. The MZW of lithium metaborate salts decreased when the stirring rate increased, but increased remarkably with increasing cooling rates and an increasing concentration of sodium chloride. The apparent secondary nucleation order for lithium metaborate salts was obtained using the Nývlt’s approach. The apparent secondary nucleation order <i>m</i> of lithium metaborate salts is 4.00 in a pure LiBO<sub>2</sub>−H<sub>2</sub>O system with an improved linear regression method. The <i>m</i> for lithium metaborate salts was enlarged in the system LiBO<sub>2</sub>−NaCl−H<sub>2</sub>O.
topic	solubility metastable zone width lithium metaborate salts nucleation order
url	https://www.mdpi.com/2073-4352/9/4/182
work_keys_str_mv	AT danli effectofimpurityionsonsolubilityandmetastablezonewidthoflithiummetaboratesalts AT yongma effectofimpurityionsonsolubilityandmetastablezonewidthoflithiummetaboratesalts AT lingzongmeng effectofimpurityionsonsolubilityandmetastablezonewidthoflithiummetaboratesalts AT yafeiguo effectofimpurityionsonsolubilityandmetastablezonewidthoflithiummetaboratesalts AT tianlongdeng effectofimpurityionsonsolubilityandmetastablezonewidthoflithiummetaboratesalts AT lanyang effectofimpurityionsonsolubilityandmetastablezonewidthoflithiummetaboratesalts
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Effect of Impurity Ions on Solubility and Metastable Zone Width of Lithium Metaborate Salts

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