Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea Groups

Sorption processes of noble metals on silica gel surface with covalently grafted N- (5-mercapto-1,3,4-thiadiazol-2-yl)- N '-propylurea groups (MTS) were studied. It was found that sorption onto MTS may occur via complexation and/or anion-exchange mechanisms depending on the acidity of the solut...

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Bibliographic Details
Main Authors: A.K. Trokhimchuk, I.M. Boychenko, V.N. Losev
Format: Article
Language:English
Published: Hindawi - SAGE Publishing 2007-02-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361707781485735
Description
Summary:Sorption processes of noble metals on silica gel surface with covalently grafted N- (5-mercapto-1,3,4-thiadiazol-2-yl)- N '-propylurea groups (MTS) were studied. It was found that sorption onto MTS may occur via complexation and/or anion-exchange mechanisms depending on the acidity of the solutions. It was shown that differences in the kinetics and temperature conditions for the sorption of platinum and gold can be used to separate micro-amounts of these metals in solution.
ISSN:0263-6174
2048-4038