(Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile

(Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile

The title compound, C32H35N3O5, is an important fluorescence probe. It is composed of a 1,4,7,10-tetraoxa-13λ2-azacyclopentadecane unit linked to a twisted (Z)-2-(4-{[(E)-2-hydroxybenzylidene]amino}phenyl)-3-phenylacrylonitrile chain. In the molecule, an O—H...N hydrogen bond forms an S(6) ring moti...

Full description

Bibliographic Details
Main Authors: Xin Zhang, Zhi-Chao Wu
Format: Article
Language:English
Published: International Union of Crystallography 2016-10-01
Series:IUCrData
Subjects:
crystal structure
azacrown ether
acrylonitrile
fluorescence probe
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616015984
id doaj-0deaa364bc5648bd846fc9dbe1fb2fb5
record_format Article
spelling doaj-0deaa364bc5648bd846fc9dbe1fb2fb52020-11-24T20:46:01ZengInternational Union of CrystallographyIUCrData2414-31462016-10-01110x16159810.1107/S2414314616015984su4074(Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrileXin Zhang0Zhi-Chao Wu1Department of Chemistry, Anhui University, Hefei 230601, People's Republic of ChinaDepartment of Chemistry, Anhui University, Hefei 230601, People's Republic of ChinaThe title compound, C32H35N3O5, is an important fluorescence probe. It is composed of a 1,4,7,10-tetraoxa-13λ2-azacyclopentadecane unit linked to a twisted (Z)-2-(4-{[(E)-2-hydroxybenzylidene]amino}phenyl)-3-phenylacrylonitrile chain. In the molecule, an O—H...N hydrogen bond forms an S(6) ring motif. There is also in intramolecular C—H...N hydrogen bond in the azacrown ether moiety, which also forms an S(6) ring motif. In the crystal, molecules are linked via pairs of C—H...O hydrogen bonds, forming inversion dimers.http://scripts.iucr.org/cgi-bin/paper?S2414314616015984crystal structureazacrown etheracrylonitrilefluorescence probehydrogen bonding
collection DOAJ
language English
format Article
sources DOAJ
author Xin Zhang
Zhi-Chao Wu
spellingShingle Xin Zhang
Zhi-Chao Wu
(Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile
IUCrData
crystal structure
azacrown ether
acrylonitrile
fluorescence probe
hydrogen bonding
author_facet Xin Zhang
Zhi-Chao Wu
author_sort Xin Zhang
title (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile
title_short (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile
title_full (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile
title_fullStr (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile
title_full_unstemmed (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile
title_sort (z)-2-(4-{[(e)-2-hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2016-10-01
description The title compound, C32H35N3O5, is an important fluorescence probe. It is composed of a 1,4,7,10-tetraoxa-13λ2-azacyclopentadecane unit linked to a twisted (Z)-2-(4-{[(E)-2-hydroxybenzylidene]amino}phenyl)-3-phenylacrylonitrile chain. In the molecule, an O—H...N hydrogen bond forms an S(6) ring motif. There is also in intramolecular C—H...N hydrogen bond in the azacrown ether moiety, which also forms an S(6) ring motif. In the crystal, molecules are linked via pairs of C—H...O hydrogen bonds, forming inversion dimers.
topic crystal structure
azacrown ether
acrylonitrile
fluorescence probe
hydrogen bonding
url http://scripts.iucr.org/cgi-bin/paper?S2414314616015984
work_keys_str_mv AT xinzhang z24e2hydroxybenzylideneaminophenyl3414710tetraoxa13azacyclopentadecan13ylphenylacrylonitrile
AT zhichaowu z24e2hydroxybenzylideneaminophenyl3414710tetraoxa13azacyclopentadecan13ylphenylacrylonitrile
_version_ 1716813341150674944

Similar Items