Ge nanocoatings as anode for three dimensional Si based Li ion microbatteries

Three dimensional (3D) hedgehog-like Ge nanoelectrodes coated on patterned Si substrate are successfully fabricated through the facile chemical vapor deposition (CVD) process. The 3D Si substrate with enlarged surface area and the abundant Ge shell electrode configuration are together favorable to e...

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Main Authors: Chuang Yue, Won Jun Chang, Won II Park, Gaozhan Liu, Jing Li
Format: Article
Language:English
Published: Elsevier 2020-01-01
Series:Electrochemistry Communications
Online Access:http://www.sciencedirect.com/science/article/pii/S1388248119302814
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spelling doaj-0d99fdb623cd427bb2436bba042869fc2020-11-25T01:19:33ZengElsevierElectrochemistry Communications1388-24812020-01-01110Ge nanocoatings as anode for three dimensional Si based Li ion microbatteriesChuang Yue0Won Jun Chang1Won II Park2Gaozhan Liu3Jing Li4Department of Microelectronics Science and Engineering, School of Physical Science and Technology, Ningbo University, Ningbo 315211, PR China; Pen-Tung Sah Institute of Micro-Nano Science and Technology, Xiamen University, Xiamen 361005, PR China; State Key Laboratory for Manufacturing Systems Engineering, Xi’an Jiaotong University, Xian 710054, PR ChinaDepartment of Materials Science and Engineering, Hanyang University, Seoul 133-791, South KoreaDepartment of Materials Science and Engineering, Hanyang University, Seoul 133-791, South Korea; Corresponding authors.Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, PR ChinaPen-Tung Sah Institute of Micro-Nano Science and Technology, Xiamen University, Xiamen 361005, PR China; Corresponding authors.Three dimensional (3D) hedgehog-like Ge nanoelectrodes coated on patterned Si substrate are successfully fabricated through the facile chemical vapor deposition (CVD) process. The 3D Si substrate with enlarged surface area and the abundant Ge shell electrode configuration are together favorable to enhance the lithiation/delithiation kinetics during cycling. Impressively, the optimized 3D Si@hedgehog-like Ge (Si@H-Ge) NRs composites anodes embrace high reversible areal capacity and superior rate capability when employed as anode material for 3D Si based lithium ion microbatteries (LIMBs). Keywords: 3D, Ge, Anode, Cyclability, Lithium ion microbatteryhttp://www.sciencedirect.com/science/article/pii/S1388248119302814
collection DOAJ
language English
format Article
sources DOAJ
author Chuang Yue
Won Jun Chang
Won II Park
Gaozhan Liu
Jing Li
spellingShingle Chuang Yue
Won Jun Chang
Won II Park
Gaozhan Liu
Jing Li
Ge nanocoatings as anode for three dimensional Si based Li ion microbatteries
Electrochemistry Communications
author_facet Chuang Yue
Won Jun Chang
Won II Park
Gaozhan Liu
Jing Li
author_sort Chuang Yue
title Ge nanocoatings as anode for three dimensional Si based Li ion microbatteries
title_short Ge nanocoatings as anode for three dimensional Si based Li ion microbatteries
title_full Ge nanocoatings as anode for three dimensional Si based Li ion microbatteries
title_fullStr Ge nanocoatings as anode for three dimensional Si based Li ion microbatteries
title_full_unstemmed Ge nanocoatings as anode for three dimensional Si based Li ion microbatteries
title_sort ge nanocoatings as anode for three dimensional si based li ion microbatteries
publisher Elsevier
series Electrochemistry Communications
issn 1388-2481
publishDate 2020-01-01
description Three dimensional (3D) hedgehog-like Ge nanoelectrodes coated on patterned Si substrate are successfully fabricated through the facile chemical vapor deposition (CVD) process. The 3D Si substrate with enlarged surface area and the abundant Ge shell electrode configuration are together favorable to enhance the lithiation/delithiation kinetics during cycling. Impressively, the optimized 3D Si@hedgehog-like Ge (Si@H-Ge) NRs composites anodes embrace high reversible areal capacity and superior rate capability when employed as anode material for 3D Si based lithium ion microbatteries (LIMBs). Keywords: 3D, Ge, Anode, Cyclability, Lithium ion microbattery
url http://www.sciencedirect.com/science/article/pii/S1388248119302814
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AT wonjunchang genanocoatingsasanodeforthreedimensionalsibasedliionmicrobatteries
AT woniipark genanocoatingsasanodeforthreedimensionalsibasedliionmicrobatteries
AT gaozhanliu genanocoatingsasanodeforthreedimensionalsibasedliionmicrobatteries
AT jingli genanocoatingsasanodeforthreedimensionalsibasedliionmicrobatteries
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