Fe-Nanoporous Carbon Derived from MIL-53(Fe): A Heterogeneous Catalyst for Mineralization of Organic Pollutants

• Main Authors: Thi Xuan Huong Le, Matthew G. Cowan, Martin Drobek, Mikhael Bechelany, Anne Julbe, Marc Cretin
• Format: Article
• Language: English
• Published: MDPI AG 2019-04-01
• Series: Nanomaterials
• Subjects: heterogeneous electro-Fenton process; metal-organic framework; dye removal; carbon; electrode
• Online Access: https://www.mdpi.com/2079-4991/9/4/641
• ISSN: 2079-4991

Catalytic electrodes were prepared via carbonization of MIL-53(Fe) on the surface of porous carbon felt electrodes (CF) for use in wastewater treatment by the heterogeneous electro-Fenton (EF) process. The best results were obtained when the carbon felt was pretreated with nitric acid, enhancing the affinity of the MIL-53(Fe) for the surface. Following a series of optimization experiments, carbonization conditions of 800 °C for 5 h were used to form Fe-nanoporous carbon (MOFs@CF). The as-prepared electrodes were used as both cathode and heterogeneous catalyst in the EF process for the mineralization of exemplar dye Acid Orange 7 (AO7). Total organic carbon (TOC) removal of 46.1% was obtained within 8 h of electrolysis at around neutral pH (6.5) and the electrode retained over 80% of its original efficiency over five treatment cycles.