Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl Complexes

Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl Complexes

In this synthesis, we have been able to show that, the addition of x- substituted pyridines, (X = H, 2- Me, 3- Me 4- Me, 4-NH2 and 4-N(CH3)2 to the dienyl ring of the organometallic cation, [(Fe(CO)3 (1-5- η-2-Me0C3H6)]BF4 and [(Fe(CO)3(1-5-η-C6H7)]BF4 gives ionic substituted diene products, (X C5...

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Main Authors: T. I. Odiaka, O. F. Akinyele, I. A. Adejoro
Format: Article
Language:English
Published: Hindawi Limited 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/781484
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spelling doaj-0d3e5d8c2dbb41db85aab76c122deb182020-11-25T00:00:22ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102011-01-018396096510.1155/2011/781484Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl ComplexesT. I. Odiaka0O. F. Akinyele1I. A. Adejoro2Department of Chemistry, University of Ibadan, Ibadan, NigeriaDepartment of Chemistry, University of Ibadan, Ibadan, NigeriaDepartment of Chemistry, University of Ibadan, Ibadan, NigeriaIn this synthesis, we have been able to show that, the addition of x- substituted pyridines, (X = H, 2- Me, 3- Me 4- Me, 4-NH2 and 4-N(CH3)2 to the dienyl ring of the organometallic cation, [(Fe(CO)3 (1-5- η-2-Me0C3H6)]BF4 and [(Fe(CO)3(1-5-η-C6H7)]BF4 gives ionic substituted diene products, (X C5H4-C6H6Y (Fe(CO)3] BF4,Y=H or 2-MeO. The reaction takes place at ordinary room temperature. The resulting products were isolated and characterized.http://dx.doi.org/10.1155/2011/781484
collection DOAJ
language English
format Article
sources DOAJ
author T. I. Odiaka
O. F. Akinyele
I. A. Adejoro
spellingShingle T. I. Odiaka
O. F. Akinyele
I. A. Adejoro
Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl Complexes
E-Journal of Chemistry
author_facet T. I. Odiaka
O. F. Akinyele
I. A. Adejoro
author_sort T. I. Odiaka
title Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl Complexes
title_short Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl Complexes
title_full Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl Complexes
title_fullStr Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl Complexes
title_full_unstemmed Synthesis and Characterization of Pyridino(1,4-Η-cyclohexa-1,3-diene)Derivatives of Iron Tricarbonyl Complexes
title_sort synthesis and characterization of pyridino(1,4-η-cyclohexa-1,3-diene)derivatives of iron tricarbonyl complexes
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2011-01-01
description In this synthesis, we have been able to show that, the addition of x- substituted pyridines, (X = H, 2- Me, 3- Me 4- Me, 4-NH2 and 4-N(CH3)2 to the dienyl ring of the organometallic cation, [(Fe(CO)3 (1-5- η-2-Me0C3H6)]BF4 and [(Fe(CO)3(1-5-η-C6H7)]BF4 gives ionic substituted diene products, (X C5H4-C6H6Y (Fe(CO)3] BF4,Y=H or 2-MeO. The reaction takes place at ordinary room temperature. The resulting products were isolated and characterized.
url http://dx.doi.org/10.1155/2011/781484
work_keys_str_mv AT tiodiaka synthesisandcharacterizationofpyridino14ēcyclohexa13dienederivativesofirontricarbonylcomplexes
AT ofakinyele synthesisandcharacterizationofpyridino14ēcyclohexa13dienederivativesofirontricarbonylcomplexes
AT iaadejoro synthesisandcharacterizationofpyridino14ēcyclohexa13dienederivativesofirontricarbonylcomplexes
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